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Titlebook: Nuclear Magnetic Resonance Spectroscopy of Cement-Based Materials; Pierre Colombet,Hélène Zanni,Piero Sozzani Conference proceedings 1998

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NMR and Infrared Spectroscopies of C-S-H and Al-Substituted C-S-H Synthesised in Alkaline Solutionsed soda solutions. The stoichiometry and spectroscopic characteristics of samples have been studied by FTIR, .A1 and .Si MAS NMR spectroscopies. The structural changes induced by substitutions have been discussed on the basis of the dreiketten structure of the tobermorite silicate chains.
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Thermochemical and Macromolecular Approach of the C-S-H Structurerometry conditions, is suggested. The elementary act of the pozzolanic reaction leads to an equality between the number of Ca atoms and the hydroxylic H.O. The hexa-coordination of Ca. leads to two supplementary molecular H.O per Ca.. This model is applied to the different basic structures Q. and a scheme is proposed for each of them.
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978-3-642-80434-2Springer-Verlag Berlin Heidelberg 1998
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Conference proceedings 1998 an important tool, not only in the study of existent cements, but also in the development of new cement-based materials. This volume, based on the proceedings of the second international conference on the NMR Spectroscopy of Cement Based Materials held in Bergamo, Italy, in June 1996, presents the
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New Progress in High Resolution 27Al and 17O Solid State NMR (MAS and MQ-MAS) of Aluminium Bearing Pally the case for .Al in aluminium bearing phases of cement interest. This contribution rapidly describes the different high resolution techniques, their acquisition and processing and shows examples of applications to aluminates, calcium aluminates and strontium aluminates.
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hus become an important tool, not only in the study of existent cements, but also in the development of new cement-based materials. This volume, based on the proceedings of the second international conference on the NMR Spectroscopy of Cement Based Materials held in Bergamo, Italy, in June 1996, pre
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