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Titlebook: Novel Metathesis Chemistry: Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailore; Y. Imamoglu,L. Bencze Conference pro

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发表于 2025-3-21 18:44:21 | 显示全部楼层 |阅读模式
书目名称Novel Metathesis Chemistry: Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailore
编辑Y. Imamoglu,L. Bencze
视频video
丛书名称NATO Science Series II: Mathematics, Physics and Chemistry
图书封面Titlebook: Novel Metathesis Chemistry: Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailore;  Y. Imamoglu,L. Bencze Conference pro
描述A comprehensive discussion of the theory, practice and application of catalytically active transition metal species and their application in the production of specialist polymeric materials. The material is presented in a progressive manner, suitable for non-experts and those seeking an introduction to the field. The bibliographies supplied are complete and up to date, making the book an indispensable guide to the primary literature for the more theoretical background to the topics discussed. .After a comprehensive discussion of initiating systems for speciality chemical synthesis the book goes on to deal with a wide range of topics in materials science, including: alkenamers, polyacetylenes, industrial applications and liquid rocket engine fuels.
出版日期Conference proceedings 2003
关键词Cadmium; Cycloaddition; ITIES; Ion; Ruthenium; carbon; catalyst; chemical synthesis; metals; polymer; rhodium;
版次1
doihttps://doi.org/10.1007/978-94-010-0066-6
isbn_softcover978-1-4020-1571-7
isbn_ebook978-94-010-0066-6Series ISSN 1568-2609
issn_series 1568-2609
copyrightSpringer Science+Business Media Dordrecht 2003
The information of publication is updating

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发表于 2025-3-21 23:55:19 | 显示全部楼层
Synthesis of Organosilicon Reagents of Vinylsilicon Functionality via Cross-Metathesis and Silylatitly stereo- and/or regio-selective reactions occur in the presence of ruthenium, rhodium and iridium complexes containing or generating the M-H and/or M-Si bonds (the silylative coupling (.)) and, in the presence of Grubbs complexes, in the case of trialkoxy- and trisiloxysubstituents at silicon (the cross-metathesis (.)).
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Ruthenium Carbenes as Catalysts for Alkene Metathesis,. generated catalysts readily prepared from easily available reagents: a ruthenium complex, an imidazolium salt and a base promote alkene and enyne metathesis. A two-component system for the polymerization of norbornene and cyclooctene is also presented.
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O,N- Bidentate Ligands Co-Ordinated on Ru-Based Olefin Metathesis Catalysts,um arene complexes has been tested on their ROMP and RCM behaviour. The obtained results suggest that the catalytic activity strongly depends on the steric and electronic environment of the Schiff Base. The different behaviour of the Schiff Base Ruthenium carbenes for ROMP and RCM has been explained.
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Synthesis of Block Copolymers and Star Polymers through Living Polymerization of Substituted Acetylhe initiation reaction is faster than propagation and the propagating species is stable. Therefore, the initiating species that have structures similar to the propagating species are preferred. Living polymerization enables the synthesis of well-defined polymers such as block copolymers, end-functionalized polymers, and star polymers.
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