Titlebook: New Synthetic Routes to Polyoxometalate Containing Ionic Liquids; An Investigation of Sven Herrmann Book 2015 Springer Fachmedien Wiesbade

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Objective,oncerning extended solvation properties, improved recyclability of catalysts or altered chemical behavior, was the main focus of this work directed to implement existing cluster structures into organic media by conversion into ionic liquids. The long term goal is to create unprecedented materials wi

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Results and Discussion,l system worked the archetypal Keggin-cluster as monolacunary anion with Cu. and Fe. embedded as additional transition metal in the lacuna. This cluster family is an ideal prototype as it offers wide coordination flexibility, good solution stability and facile synthetic access.

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Summary and Perspective,n order to create a basis for further studies of this relatively new compound class. Polyoxometalates being purely inorganic compounds could be of high interest for industrial use due to their stability and promising examples in catalysis and materials science. Transfer into organic reaction media i

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