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Titlebook: Natural Product Synthesis II; Targets, Methods, Co Johann Mulzer Book 2005 Springer-Verlag Berlin Heidelberg 2005 Alcaloids.Aza-Claisen.Cla

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Occurrence, Biological Activity, and Convergent Organometallic Synthesis of Carbazole Alkaloids,iated oxidative coupling of arylamines with unsaturated six-membered hydrocarbons, thus leading to highly convergent total syntheses of the envisaged natural products. The advantages of this strategy, as well as the scope and limitations of the different procedures, are discussed.
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Recent Advances in Vinylogous Aldol Reactions and Their Applications in the Syntheses of Natural Pr acetals in both aldehyde and enolate activation. In particular, aliphatic aldehydes give poor yields and selectivities. Protocols for the enantioselective variation are given using either the Tol-BINAP system or .-symmetrical copper(II) complexes.
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