Titlebook: N4-Macrocyclic Metal Complexes; José H. Zagal,Fethi Bedioui,Jean-Pol Dodelet Book 2006 Springer-Verlag New York 2006 biomimetic.catalysis.

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Photoelectrochemical Reactions at Phthalocyanine Electrodes,le-crystalline inorganic semiconductors. Subsequent research also tried to explore new systems of acceptable efficiency and stability at a more affordable price. The use of amorphous inorganic semiconductors or materials grown as thin films was one strategy, the use of organic semiconductors another.

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Electroreduction of CO2 Catalyzed by Metallomacrocyclics,nthesis of ecologic fuels or the control of the greenhouse effect, responsible for the natural environment disruption. Carbon dioxide fixation is an important area of research, oriented to overcome problems related to the global environment and to the depletion of fossil fuels.

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Supramolecular Porphyrins as Electrocatalysts,. In addition, the properties of the inserted metal complexes can be varied almost at will, thanks to the large number of metallic elements associated with a plethora of available oxidation states and ligands.

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Organized Multiporphyrinic Assemblies for Photoconduction and Electroconduction,s from which they originate. While extremely well-defined geometries can be obtained by covalent synthesis, providing useful structure–activity information, self-assembly of photo and electroactive species is attractive because of its simplicity. This chapter is meant to demonstrate the complementarity of both approaches.

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Fundamental Aspects on the Catalytic Activity of Metallomacrocyclics for the Electrochemical Reductt be present in the atmosphere. Molecular oxygen is generated by photosynthesis on earth and in the sea, so it can be considered a by-product of some living organisms and other living organisms profit from the free energy available from this molecule to sustain aerobic life. So molecular oxygen is a