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Titlebook: N-Heterocyclic Carbenes in Transition Metal Catalysis; Frank Glorius Book 2007 Springer-Verlag Berlin Heidelberg 2007 Heterocyclic Chemist

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发表于 2025-3-21 18:43:19 | 显示全部楼层 |阅读模式
书目名称N-Heterocyclic Carbenes in Transition Metal Catalysis
编辑Frank Glorius
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概述Each volume of Topics in Organometallic Chemistry provides the broad scientific readership with a comprehensive summary and critical overview of a specific topic in organometallic chemistry.Research i
丛书名称Topics in Organometallic Chemistry
图书封面Titlebook: N-Heterocyclic Carbenes in Transition Metal Catalysis;  Frank Glorius Book 2007 Springer-Verlag Berlin Heidelberg 2007 Heterocyclic Chemist
描述.It was only in the early 1990s that carbenes with the carbene carbon being incorporated in a nitrogen containing heterocycle (N-heterocyclic carbenes or NHCs) were found to be stable enough to be isolated. Since the first report on the application of NHCs as ligands in transition metal catalysis in 1995, NHC have found numerous applications and have been established as a versatile and indispensable class of ligands. For many reactions like metathesis or cross-coupling reactions NHCs have often become the ligands of choice, allowing otherwise difficult transformations. In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes. The use of NHC as ligands in catalysis has reached a certain level of maturity and this book allows the reader to get a balanced view of this increasingly important ligand class..
出版日期Book 2007
关键词Heterocyclic Chemistry; Medicinal Chemistry; Organometallic Chemistry; Oxidation; catalysis
版次1
doihttps://doi.org/10.1007/978-3-540-36930-1
isbn_softcover978-3-642-07197-3
isbn_ebook978-3-540-36930-1Series ISSN 1436-6002 Series E-ISSN 1616-8534
issn_series 1436-6002
copyrightSpringer-Verlag Berlin Heidelberg 2007
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发表于 2025-3-21 22:16:09 | 显示全部楼层
https://doi.org/10.1007/978-3-540-36930-1Heterocyclic Chemistry; Medicinal Chemistry; Organometallic Chemistry; Oxidation; catalysis
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,N-Heterocyclic Carbenes in Catalysis—An Introduction,N-Heterocyclic carbene (NHC) has become a major ligand class and has proven to be more than just a “phosphine mimic”. Some important features like electronic and steric properties are discussed and typical examples of NHC are given herein.
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978-3-642-07197-3Springer-Verlag Berlin Heidelberg 2007
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N-Heterocyclic Carbenes in Transition Metal Catalysis978-3-540-36930-1Series ISSN 1436-6002 Series E-ISSN 1616-8534
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Routes to N-Heterocyclic Carbene Complexes,; (3) use of preformed, isolated free carbenes; (4) deprotonation of an azolium salt with a base; (5) transmetallation from an Ag — NHC complex prepared from direct reaction of an imidazolium precursor and Ag2O; and (6) oxidative addition via activation of the C2 — X (X = Me, halogen, H) of an imidazolium cation.
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