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Titlebook: Metathesis Chemistry; From Nanostructure D Yavuz Imamoglu,Valerian Dragutan,Solmaz Karabulut Conference proceedings 20071st edition Springe

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楼主: Ingrown-Toenail
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Ruthenium–Vinylidene Complexes: An Efficient Class of Homogeneous Metathesis Catalystsials. The successful application of Ru–vinylidenes as efficient pre-catalysts for the synthesis of carbocyclic and heterocyclic compounds by ring-closing metathesis (RCM) of αω, -dienes, and in the synthesis of polymers by ring-opening metathesis polymerization (ROMP) of cyclooctene, norbornene, 5-s
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“Greener Shade of Ruthenium”: New Concepts of Activation, Immobilization, and Recovery of Ruthenium awing groups (EWGs) without detriment to catalysts stability. This principle can be used not only to increase the catalyst activity, but also to alter its physical–chemical properties, such as solubility in given medium or affinity to silica gel. An example of novel immobilisation strategy, based on
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Ring-Opening Metathesis Activity of Ruthenium-Based Olefin Metathesis Catalyst Coordinated with 1,3-l)2Ru=CHPh (2). The catalytic performance of catalyst (4) is checked on ring-opening metathesis polymerization (ROMP) of the low strain monomer, cycloocta-1,5-diene (COD), and also compared with catalyst (2) and (3).
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