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Titlebook: Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations; Bernard Meunier Book 2000 Springer-Verlag Berlin Heidelberg 2000 Biochemie.Bio

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Characterization, Orbital Description, and Reactivity Patterns of Transition-Metal Oxo Species in t metal-oxo species and their properties which turn out to be of prime importance for the understanding of the observed reactivity patterns. A second topic concerns higher transition-metal oxides such as di- and trioxides. For these species there exists a structural dichotomy with the corresponding d
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Characterization and Properties of Non-Heme Iron Peroxo Complexes,rm of the catalytic site in many mono-iron biomolecules. To the same peroxidic level correspond, in diiron enzymes, bridged peroxo Fe(III)-O-O-Fe(III) intermediates. This review is concerned with the preparation and spectroscopic characterization of such intermediates in non-heme chemical systems, t
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Copper-Dioxygen and Copper-Oxo Species Relevant to Copper Oxygenases and Oxidases,ononuclear, dinuclear, and trinuclear copper centers, with the copper ions displaying a variety of coordination numbers and stereochemistries. Information regarding the mechanism by which these proteins activate dioxygen has been obtained by studies of the reactions of small molecule model copper co
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Nature of Activated Bleomycin,also forms in reactions of bleomycin with Fe(III) and peroxide, or bleomycin with superoxide and either Fe(III) or Fe(II). Efforts to characterize this transient species proceeded by kinetic and spectroscopic strategies. Activated bleomycin now appears to be a drug-ferric-peroxide complex, but this
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978-3-662-15663-6Springer-Verlag Berlin Heidelberg 2000
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Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations978-3-540-46592-8Series ISSN 0081-5993 Series E-ISSN 1616-8550
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Bernard MeunierThis series presents critical reviews of the present position and future trends in modern chemical research.Short and concise reports on chemistry, each written by the world‘s renowned experts. Still
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