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Titlebook: Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations; Bernard Meunier Book 2000 Springer-Verlag Berlin Heidelberg 2000 Biochemie.Bio

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书目名称Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations
编辑Bernard Meunier
视频video
概述This series presents critical reviews of the present position and future trends in modern chemical research.Short and concise reports on chemistry, each written by the world‘s renowned experts. Still
丛书名称Structure and Bonding
图书封面Titlebook: Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations;  Bernard Meunier Book 2000 Springer-Verlag Berlin Heidelberg 2000 Biochemie.Bio
描述The present volume is a description of the current knowledge on the different metal-oxo and metal-peroxo species which are involved in catalytic oxidations. These highly reactivity metal-oxygen species are the key intermediates in heme or non-heme oxygenases, as well as in metal-catalyzed oxidations. The accumulated knowledge on these reactive entities will facilitate a better understanding of the different intermediates involved in the catalytic cycles of enzymes like cytochromes P-450, non-heme oxygenases, copper oxygenases, in the oxidation of water by the manganese-center of Photosystem II, in the chemistry of dioxiranes and also in DNA cleavage performed by activated bleomycin. The description of these metal-oxo and metal-peroxo species is based on physico-chemical data, reactivity results and also on theoretical calculations.
出版日期Book 2000
关键词Biochemie; Biochemistry; Catalytic Oxydations; Catalytische Oxidation; Metallorganische Chemie; Organomet
版次1
doihttps://doi.org/10.1007/3-540-46592-8
isbn_softcover978-3-662-15663-6
isbn_ebook978-3-540-46592-8Series ISSN 0081-5993 Series E-ISSN 1616-8550
issn_series 0081-5993
copyrightSpringer-Verlag Berlin Heidelberg 2000
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Characterization, Orbital Description, and Reactivity Patterns of Transition-Metal Oxo Species in tls to mediate surface crossings via spin-orbit coupling is introduced as a key aspect in oxidation catalysis which has as yet not been fully appreciated. It is further outlined how these fundamental properties may relate to the properties of metal-oxo catalysts in the condensed phase.
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Characterization of High-Valent Oxo-Metalloporphyrins,lication to biological systems are summarized. In the Sects. 4 and 5, synthesis and characterization of oxo chromium and oxo ruthenium porphyrin complexes are reviewed. In the last section, we have summarized the synthesis and characterization of Mo, Nb, Ti, and V oxo metalloporphyrins complexes.
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0081-5993 mistry, each written by the world‘s renowned experts. Still The present volume is a description of the current knowledge on the different metal-oxo and metal-peroxo species which are involved in catalytic oxidations. These highly reactivity metal-oxygen species are the key intermediates in heme or n
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Book 2000tions. These highly reactivity metal-oxygen species are the key intermediates in heme or non-heme oxygenases, as well as in metal-catalyzed oxidations. The accumulated knowledge on these reactive entities will facilitate a better understanding of the different intermediates involved in the catalytic
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