| 书目名称 | Metal Vapour Synthesis in Organometallic Chemistry | | 编辑 | John R. Blackborow,Dennis Young | | 视频video | | | 丛书名称 | Reactivity and Structure: Concepts in Organic Chemistry | | 图书封面 |  | | 描述 | Metal Vapour Synthesis (MVS) can be defined as; "The use in synthesis of high temper ature gaseous species such as metal atoms by their reactions with themselves or other materials in a condensed phase. " This short book, covering the literature up to the middle of 1979, describes MVS in organic chemistry; i. e. the reactions of metal atoms with various, predominantly organic, substrates in the synthesis and reactivity studies of organic and organometallic compounds. In order to effectively describe all the underlying principles and to present a coesive picture of pertinent metal atom processes in condensed organic phases, some inorganic substrates such as rare gases, dinitrogen, dioxygen, dihalo gens, and inorganic halides have been included. For similar reasons, we have used, where relevent, information provided by the closely related technique of Matrix Isolation Spec troscopy (MIS). After an introductory chapter which gives the basis principles and includes a brief critique of the technique, the book is divided into three further chapters dealing respec tively with (a) experimental techniques, (b) behaviour of metal atoms in matrices, and (c) results of prep~rative experime | | 出版日期 | Book 1979 | | 关键词 | Alkene; Metallorganische Verbindung; Synthese; alkyne; carbon; carbon dioxide; isolation; metals; organometa | | 版次 | 1 | | doi | https://doi.org/10.1007/978-3-642-67285-9 | | isbn_softcover | 978-3-642-67287-3 | | isbn_ebook | 978-3-642-67285-9Series ISSN 0341-2377 | | issn_series | 0341-2377 | | copyright | Springer-Verlag Berlin Heidelberg 1979 |
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发表于 2025-3-21 19:18:50
