Titlebook: Metal Promoted Selectivity in Organic Synthesis; A. F. Noels,M. Graziani,A. J. Hubert Book 1991 Kluwer Academic Publishers 1991 Coupling r

Aids209

probate

Industrial Aspects of Selectivity Applying Homogeneous Catalysis,mplies that search for selectivity provides a great challenge to the chemical industry necessitating substantial research and development efforts. In aiming at selectivity, catalysis plays an important role. In the last decades, homogeneous transition metal based catalysts have emerged as especially promising in obtaining selectivity.

与野兽博斗者

Palladium Catalyzed Reduction of Aryl Sulfonates. Selectivity Control and Application to Anthracyclanthracyclines these molecules consist of an aglycone moiety and an aminosugar joined through a glycosidic bond at C-7; the two structures differ only at C-14 where daunorubicin bears a methyl group and doxorubicin an hydroxymethyl moiety (Figure 1).

饥荒

jungle

Catalytic Carbonylations of Nitrogen Containing Organic Compounds,1]. On the other hand different routes to the metal promoted C-N bond formation lead to a different type of products. These catalytic syntheses involve the interaction of carbon monoxide with organic azides, RN. [2–4], with aromatic nitro compounds, ArNO. [5], and with amines in the presence of molecular oxygen [6–8] (Scheme 1).

铁塔等

散布

To Which Extent do Phosphanes Induce Selectivity in C-C Bond Formation?,y all the metals of the periodic table stabilized in various oxidation states by hydride, carbonyl, nitrosyl, alkyl, alkene, alkynes, arenes … ligands are capable of accomodating phosphoranes, ., phosphines, ., phosphites, ., phosphides, ., phosphinidenes, ., etc.

巧办法

软弱

The Design of a Chemoselective Reduction Catalyst, obtained in α, β -unsaturated ketones, where the olefinic double bond is invariably affected. Only recently has this reaction been reported to be promoted by Cp.ZrH. and Cp.HfH., to give selective carbonyl group reduction in hydrogen transfer reaction using propan-2-ol as source of hydrogen [6].

Indicative

ants in topology,q-special functions, conformal field theory,quantumintegrable models. The aim of the Euler Institute‘sworkshops was to review and compile the progress achieved inthe different subfields. Near 100 participants came from 14countries. More than 20 contributionswritten up for thisbook c