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Titlebook: Metal Promoted Selectivity in Organic Synthesis; A. F. Noels,M. Graziani,A. J. Hubert Book 1991 Kluwer Academic Publishers 1991 Coupling r

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书目名称Metal Promoted Selectivity in Organic Synthesis
编辑A. F. Noels,M. Graziani,A. J. Hubert
视频video
丛书名称Catalysis by Metal Complexes
图书封面Titlebook: Metal Promoted Selectivity in Organic Synthesis;  A. F. Noels,M. Graziani,A. J. Hubert Book 1991 Kluwer Academic Publishers 1991 Coupling r
描述The demand for selective organic reactions is growing more acute everyday. Indeed, greater product selectivity has an important impact on energy and resource utilization, in terms of reduced process energy requirements for product separation and purification, in terms of low-value by-products, and in terms of environmental acceptance and compatibility. Moreover, more and more chemicals, especially pharmaceuticals, have to be sold in an optically active form. The search for selectivity constitutes a tremendous challenge for the chemists. In the last two decades, homogeneous transition metal based catalysis has emerged as one of the most promising tools for obtaining selectivity. In connection with developments in this area, this book contains updated and expanded versions of most of the lectures presented at a Cornett course held in Trieste (Italy) in 1989 and sponsored by the European Community. A primary aim is to cultivate a deeper understanding of the parameters that govern the selectivities and stimulate a wider utilization of transition metal based catalysis in organic synthesis. All aspects of selectivity, chemo-, regio-, stereo- and enantioselectivity are considered and illu
出版日期Book 1991
关键词Coupling reaction; Ene reaction; Leaving group; Rearrangement; catalysis; nucleophile; spectroscopy
版次1
doihttps://doi.org/10.1007/978-94-011-3408-8
isbn_softcover978-94-010-5508-6
isbn_ebook978-94-011-3408-8Series ISSN 0920-4652 Series E-ISSN 2215-180X
issn_series 0920-4652
copyrightKluwer Academic Publishers 1991
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Enantioselective ,-Oxidation: Synthetic Applications,The homochiral sulfinyl group, owing to its ability to promote and to direct reactions taking place at the adjacent carbon atoms, has been widely used in synthetic procedures [1], A few typical examples taken from the recent literature are shown in Scheme 1.
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Selective Stoichiometric Reductions of Organic Functional Groups by Aqueous Metal Ions. ImplicationIt is well known that the selectivity of a catalyst is a kinetic phenomenon, . it is based on differences in rate. The archetype is Maxwell’s demon, a creature endowed with the ability of shorting out fast from slow moving molecules.
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Carbonylchromium(O) Complexes in Organic Synthesis,The title topic is very extensive and many papers are published in this field every year. The aim of this presentation is to pick out from such literature information necessary to give an overall picture of the chemical behaviour of carbonylchromium(0)complexes and of their utilization in synthesis.
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