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Titlebook: Metal Catalyzed Cascade Reactions; Thomas J. J. Müller Book 2006 Springer-Verlag Berlin Heidelberg 2006 Organometallic chemistry.Ruthenium

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发表于 2025-3-21 19:27:11 | 显示全部楼层 |阅读模式
书目名称Metal Catalyzed Cascade Reactions
编辑Thomas J. J. Müller
视频video
概述Each volume of Topics in Organometallic Chemistry provides the broad scientific readership with a comprehensive summary and critical overview of a specific topic in organometallic chemistry..Research
丛书名称Topics in Organometallic Chemistry
图书封面Titlebook: Metal Catalyzed Cascade Reactions;  Thomas J. J. Müller Book 2006 Springer-Verlag Berlin Heidelberg 2006 Organometallic chemistry.Ruthenium
描述.Transition metal-catalyzed cascade reactions are an elegant approach to complex molecular scaffolds. Besides their esthetics and increase in structural complexity, they have also become mechanistic challenges for the combination of organometallic elementary steps. As a consequence, cascade reactions have revolutionized synthetic strategies and conceptual thinking. The authors highlight cyclization via carbopalladation and acylpalladation and Heck-pericyclic sequences. They discuss p-allyl palladium-based cascade reactions, Michael-type additions as an entry to transition-metal-promoted cyclizative transformations, and sequential or consecutive palladium-catalyzed processes, and show Pauson-Khand cascades, metal-catalyzed cyclizations of acyclic precursors, as well as cascade and sequential ruthenium-catalyzed transformations. Therefore, the reader finds overview of an exciting and highly dynamic field of a new and innovative methodological concept..
出版日期Book 2006
关键词Organometallic chemistry; Ruthenium; catalysis; inorganic chemistry; metals; palladium; transition metal
版次1
doihttps://doi.org/10.1007/11603696
isbn_softcover978-3-642-06950-5
isbn_ebook978-3-540-32959-6Series ISSN 1436-6002 Series E-ISSN 1616-8534
issn_series 1436-6002
copyrightSpringer-Verlag Berlin Heidelberg 2006
The information of publication is updating

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发表于 2025-3-21 22:57:39 | 显示全部楼层
Domino Heck-Pericyclic Reactions,es to build up complex molecular skeletons from simpleprecursors. The intermolecular Heck reaction of alkenyl halides with alkenes leads to 1,3-butadienesprone to undergo subsequent Diels–Alder reactions. Frequently, special precautions have tobe taken in order to avoid a domino reaction in which th
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,Palladium Catalyzed Cascade Reactions Involving π-Allyl Palladium Chemistry,atalytic generation of π-allyl palladiumintermediates which further undergo a variety of reactions. π-Allyl palladium complexescan be easily formed by the treatment of allylic substrates with Pd(0). A π-allyl palladiumcomplexes on treatment with allylic metal species produce bis π-allyl palladium co
发表于 2025-3-22 04:53:47 | 显示全部楼层
The Virtue of Michael-Type Addition Processes in the Design of Transition Metal-Promoted Cyclizativd polycyclic structures. In thisreview, recent advances in this field are presented. The first part is related to cycloaddition reactionsbased on zwitterionic . − .-allylPdcomplexes. The second part deals with Michael initiated metal-catalyzed cyclofunctionalization reactionsof unactivated . − .′-bo
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Sequentially Palladium-Catalyzed Processes, occur in a sequential or consecutivefashion in the same reaction vessel without addition of further amounts of catalyst to the reactionmedia. This novel type of cascade reaction can be elaborated into both domino and multicomponentprocesses and represents a significant contribution to the highly to
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this frequently identified “urban challenge” has been recognized and addressed increasingly in urban studies, as well as in transformation studies. However, while both fields clearly overlap and effectively complement each other in this regard, the respective epistemic communities have largely remai
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Ei-ichi Negishi,Guangwei Wang,Gangguo Zhuthis frequently identified “urban challenge” has been recognized and addressed increasingly in urban studies, as well as in transformation studies. However, while both fields clearly overlap and effectively complement each other in this regard, the respective epistemic communities have largely remai
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