书目名称 | Metal Catalyzed Cascade Reactions | 编辑 | Thomas J. J. Müller | 视频video | | 概述 | Each volume of Topics in Organometallic Chemistry provides the broad scientific readership with a comprehensive summary and critical overview of a specific topic in organometallic chemistry..Research | 丛书名称 | Topics in Organometallic Chemistry | 图书封面 |  | 描述 | .Transition metal-catalyzed cascade reactions are an elegant approach to complex molecular scaffolds. Besides their esthetics and increase in structural complexity, they have also become mechanistic challenges for the combination of organometallic elementary steps. As a consequence, cascade reactions have revolutionized synthetic strategies and conceptual thinking. The authors highlight cyclization via carbopalladation and acylpalladation and Heck-pericyclic sequences. They discuss p-allyl palladium-based cascade reactions, Michael-type additions as an entry to transition-metal-promoted cyclizative transformations, and sequential or consecutive palladium-catalyzed processes, and show Pauson-Khand cascades, metal-catalyzed cyclizations of acyclic precursors, as well as cascade and sequential ruthenium-catalyzed transformations. Therefore, the reader finds overview of an exciting and highly dynamic field of a new and innovative methodological concept.. | 出版日期 | Book 2006 | 关键词 | Organometallic chemistry; Ruthenium; catalysis; inorganic chemistry; metals; palladium; transition metal | 版次 | 1 | doi | https://doi.org/10.1007/11603696 | isbn_softcover | 978-3-642-06950-5 | isbn_ebook | 978-3-540-32959-6Series ISSN 1436-6002 Series E-ISSN 1616-8534 | issn_series | 1436-6002 | copyright | Springer-Verlag Berlin Heidelberg 2006 |
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