Titlebook: Mechanisms of Polymer Degradation and Stabilisation; Gerald Scott (Professor of Polymer Science) Book 1990 Elsevier Science Publishers Ltd

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A Theoretical Approach to the Optimisation of Antioxidant Action,e RH, on the reactivity of radicals and In., on the stability of the hydroperoxide ROOH and on the oxidation conditions. The mechanism is determined by the key steps of the radical chain oxidation reaction and this is in turn determined by the bond energies of R—H and In—H. The rate constants of the

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Mechanisms of Antioxidant Action of Phosphite and Phosphonite Esters,cations. They function as antioxidants by various mechanisms depending on their structure, the nature of the substrate to be stabilised and the reaction conditions..All phosphites and phosphonites are hydroperoxide-decomposing secondary antioxidants. Their reactivity in hydroperoxide reduction decre

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Polymers and High-Energy Irradiation: Degradation and Stabilization,causing polymer degradation. In addition slow, post-irradiation reactions are discussed as they relate to deterioration during storage. Potential methods of polymer stabilization against high-energy radiation are then reviewed from the viewpoints of electron and ion scavenging, energy transfer proce

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g systems for a wide range of polymers and applications. A complemen­ tary and ultimately more important objective is to accommodate these practical developments within the framework of antioxidant theory, since there can be little question that further major advances in the practice of stabilisatio

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