Titlebook: Mechanisms of Inorganic and Organometallic Reactions; Volume 8 M. V. Twigg Book 1994 Springer Science+Business Media New York 1994 Substitu

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Substitution Reactions of Labile Metal Complexesigands and then constrasts this with the special features to be considered for macrocyclic ligands. While for crown ether complexes there is normally some residual interaction between the metal center and solvent, this contrasts with cryptate formation, where there is an additional step involving sh

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Reactivity of Coordinated Ligandsn sections. The first deals with coordination complexes of cobalt(III), the second with complexes of other metal centers, and the last with ligand reactions of organometallic compounds. The emphasis is on stoichiometric reactions. Catalytic processes, particularly those involving organometallic spec

phytochemicals

Rearrangements, Intramolecular Exchanges, and Isomerizations of Organometallic Compoundsternal molecular dynamics reported here have again been studied by one- and two-dimensional NMR methods, the particular choice of technique depending on the time scale of the dynamic process being studied. Two especially pertinent reviews of NMR methods applied to molecular stereodynamics of organom

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Homogeneous Catalysis of Organic Reactions by Transition Metal Complexeslysis and pointed out a number of industrial-scale applications, such as olefin carbonylations, the hydroformylation of formaldehyde and of olefins, the reductive carbonylation of aromatics and olefin dimerisation.. An extensive review compiles and critially evaluates thermodynamic data on transitio

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Volumes of Activation for Inorganic and Organometallic Reactions: A Tabulated Compilationarious groups. During the compilation of this contribution we encountered many interesting papers dealing with the general application of high-pressure techniques in the study of inorganic and organometallic systems. Since these do not involve the determination of activation and reaction volumes, they will only be referred to in a general way.