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Titlebook: Mechanisms of Inorganic and Organometallic Reactions; Volume 8 M. V. Twigg Book 1994 Springer Science+Business Media New York 1994 Substitu

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of inorganic and organometallic reactions. The main focus is on reactions in solution, although solid-state and gas-phase studies are included where they provide relevant mechanistic insight. Each volume covers an eighteen-month literature period, and this, the eighth volume in the series, includes
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Substitution Reactions of Inert-Metal Complexes—Coordination Numbers 6 and Above: Other Inert Centerigations reveal, through reversibility or irreversibility, lability of appropriate systems in one or other oxidation state. A few studies of this nature are cited here, but only when they seem to supply significant mechanistic information.
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Substitution Reactions of Labile Metal Complexesthe metal ion is still almost fully solvated, and interaction with the N-donors is the final stage of complexation, corresponding to exclusive-to-inclusive complex formation. Cryptand formation by Ag., however, is more specific, involving Ag.-to-N bond formation as the first steps after outer-sphere complex formation.
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Substitution and Insertion Reactionslength elsewhere.. Another brief survey of the reactivities of metal carbonyls also appeared. in the “Mond Centenary” volume. It tends not to recognize the importance of steric effects on reactivity and the wide occurrence of associative reactions, especially of metal carbonyl clusters, but even of mononuclear some binary carbonyls..
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Substitution Reactions of Inert-Metal Complexes—Coordination Numbers 6 and Above: Chromiumew of the photophysics of chromium(III) complexes. and, more specifically, the photochemical water-exchange process in chromium(III) complexes.. A summary of new insights into the mechanism of spontaneous and base-catalyzed substitution reactions of inert-metal amine complexes has also appeared..
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Book 1994nic and organometallic reactions. The main focus is on reactions in solution, although solid-state and gas-phase studies are included where they provide relevant mechanistic insight. Each volume covers an eighteen-month literature period, and this, the eighth volume in the series, includes papers pu
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