书目名称 | Matrix Isolation Spectroscopy | 编辑 | A. J. Barnes,W. J. Orville-Thomas,R. Gaufrès | 视频video | | 丛书名称 | Nato Science Series C: | 图书封面 |  | 描述 | The matrix isolation (MI) method has now been used for nearly thirty years. During this period it has been actively developed and the range of problems tackled greatly extended. Originally it was used for studies of transient species involv ing vibrational, electronic and ESR spectroscopy. Nowadays the study of transient species forms a comparatively small part of HI work since it has been amply demonstrated that very fruitful information can be obtained of the structure and interactions of stable molecules and their aggregates. In addition to the s~ectroscopic methods mentioned above the MI technique is nowadays a standard method in research based on vibrational relaxation, luminescence, Mossbauer, magnetic circular dichroism, pulsed NMR and photoelectron spectroscopy. The matrix isolation technique affords considerable advantages over more conventional methods in most applications of spectroscopy. Areas where the technique has been widely applied, or shows great potential, include: metal atom chemistry, and its relation to surface chemistry, high temperature inorganic species, transition metal complexes, interstellar species, free radicals and unstable molecules, conformational | 出版日期 | Book 1981 | 关键词 | Conformational isomerism; Isomer; Mössbauer spectroscopy; chemistry; spectroscopy; spin | 版次 | 1 | doi | https://doi.org/10.1007/978-94-009-8540-7 | isbn_softcover | 978-94-009-8542-1 | isbn_ebook | 978-94-009-8540-7Series ISSN 1389-2185 | issn_series | 1389-2185 | copyright | D. Reidel Publishing Company, Dordrecht, Holland 1981 |
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