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Titlebook: Magnetic Properties of Transition Metal Compounds; Richard L. Carlin,A. J. Duyneveldt Book 1977 Springer Science+Business Media New York 1

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书目名称Magnetic Properties of Transition Metal Compounds
编辑Richard L. Carlin,A. J. Duyneveldt
视频video
丛书名称Inorganic Chemistry Concepts
图书封面Titlebook: Magnetic Properties of Transition Metal Compounds;  Richard L. Carlin,A. J. Duyneveldt Book 1977 Springer Science+Business Media New York 1
描述This is a textbook of what is often called magnetochemistry. We take the point of view that magnetic phenomena are interesting because of what they tell us about chemical systems. Yet, we believe it is no longer tenable to write only about such subjects as distinguishing stereochemistry from the measurement of a magnetic susceptibility over a restricted temper­ ature region; that is, paramagnetism is so well-understood that little remains to explore which is of fundamental interest. The major purpose of this book is to direct chemists to some of the recent work of physicists, and in particular to a lengthy exposition of magnetic ordering phenomena. Chemists have long been interested in magnetic interactions in clusters, but many have shied away from long-range ordering phenomena. Now however more people are investigating magnetic behavior at temperatures in the liquid helium region, where ordering phenomena can scarcely be avoided. The emphasis is on complexes of the iron-series ions, for this is where most of the recent work, both experimental and theoretical, has been done. The discussion therefore is limited to insulating crystals; the nature of magnetism in metals and such mate
出版日期Book 1977
关键词Magnetismus; copper; iron; lanthanum; manganese; metals; nickel; stereochemistry; transition element; transit
版次1
doihttps://doi.org/10.1007/978-3-642-87392-8
isbn_softcover978-3-642-87394-2
isbn_ebook978-3-642-87392-8Series ISSN 0172-7966
issn_series 0172-7966
copyrightSpringer Science+Business Media New York 1977
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Selected Examples,erstood or most important ones, a knowledge of which should be had by everyone interested in this subject. We begin by briefly summarizing the single-ion properties of those ions which form compounds discussed below. Further information and references may be found in earlier sections of the book, as well as in Refs. 1–6.
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Book 1977ll us about chemical systems. Yet, we believe it is no longer tenable to write only about such subjects as distinguishing stereochemistry from the measurement of a magnetic susceptibility over a restricted temper­ ature region; that is, paramagnetism is so well-understood that little remains to expl
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Paramagnetism: Zero-Field Splittings,at behavior, and limit the usefulness of certain substances for adiabatic demagnetization. Furthermore, zero-field splittings cause a single-ion anisotropy which is important in characterizing anisotropic exchange, and are also one of the sources of canting or weak ferromagnetism (Chapt. VII).
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Short-Range Order,nge order,” which, while quite accurate, is not very useful. For operational purposes, the term will be restricted to magnetic interactions in one and two dimensions. In that regard, it is interesting to note that the entire discussion is thereby restricted to the . region.
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