| 书目名称 | Late Transition Metal-Carboryne Complexes |
| 副标题 | Synthesis, Structure |
| 编辑 | Zaozao Qiu |
| 视频video | |
| 概述 | Nominated by The Chinese University of Hong Kong as an outstanding PhD thesis.Ground-breaking new work in metal-carboryne chemistry.Inspiration for future work on synthetic, cluster and materials chem |
| 丛书名称 | Springer Theses |
| 图书封面 |  |
| 描述 | Zaozao Qiu shows in this thesis that transition metals can mediate or catalyze the cycloaddition or coupling reactions of carboryne with alkynes or alkenes to afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes. These results represent powerful strategies to assemble useful complex molecules from very simple precursors in a single operation. Carboranes have many applications in medicine. However, their unique structures make derivatization difficult and the limited efficient synthetic methods to obtain functional carborane materials have restricted applications of carboranes within a narrow scope. This work breaks a new ground in metal-carboryne chemistry and will have a significant impact on synthetic, cluster and materials chemistry. |
| 出版日期 | Book 2012 |
| 关键词 | carborane; carboryne; coupling reaction; cycloaddition reaction; metal-carboryne; prize thesis |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-3-642-24361-5 |
| isbn_softcover | 978-3-642-43502-7 |
| isbn_ebook | 978-3-642-24361-5Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
| issn_series | 2190-5053 |
| copyright | The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer-Verlag GmbH, DE |
发表于 2025-3-21 16:04:37
