| 书目名称 | Kinetics and Spectroscopy of Carbenes and Biradicals |
| 编辑 | Matthew S. Platz |
| 视频video | http://file.papertrans.cn/544/543065/543065.mp4 |
| 图书封面 |  |
| 描述 | The development of mechanistic organic chemistry is filled with claims of short-lived reactive intermediates connecting starting material to product. In many ways this book represents a personal odyssey of the editor in this area of chemistry. I well remember my introduction to organic chemistry as an undergraduate working in the laboratories of Shelton Bank at SUNY Albany in the early 1970s, and the excitement and frustration attending the piecing together of the details of a reaction mechanism by working backwards from the stable products of the reaction. In those days the reaction and the reactive intermediates flew by too rapidly to permit direct observation. Thus it came as something of a revelation to me as a graduate student at Yale that it was possible to slow down a reaction and actually "see" such ephemeral species as carbenes and biradicals by spectroscopic methods, by generating them photochemically at cryogenic temperatures. In this monograph several chap ters are devoted to low-temperature studies. Dougherty has described the matrix EPR spectra of biradicals, which were pure conjecture only ten years ago. Michl and Arnold have described the matrix spectroscopy of cyc |
| 出版日期 | Book 1990 |
| 关键词 | aromatic; kinetics; organic chemistry; spectroscopy; structure |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-1-4899-3707-0 |
| isbn_softcover | 978-1-4899-3709-4 |
| isbn_ebook | 978-1-4899-3707-0 |
| copyright | Springer Science+Business Media New York 1990 |
|Archiver|手机版|小黑屋|
派博传思国际
( 京公网安备110108008328)
GMT+8, 2025-8-10 02:19
发表于 2025-3-21 16:28:40
