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Titlebook: Kinetically Controlled Stepwise Syntheses of a Heterometallic Complex and a Tetrahedral Chiral-at-Me; Kenichi Endo Book 2021 The Editor(s)

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发表于 2025-3-21 17:45:08 | 显示全部楼层 |阅读模式
书目名称Kinetically Controlled Stepwise Syntheses of a Heterometallic Complex and a Tetrahedral Chiral-at-Me
编辑Kenichi Endo
视频video
概述Nominated as an outstanding Ph.D. thesis by the University of Tokyo.Presents synthetic strategies for metal complexes in detail.Introduces unique techniques to distinguish similar complexes
丛书名称Springer Theses
图书封面Titlebook: Kinetically Controlled Stepwise Syntheses of a Heterometallic Complex and a Tetrahedral Chiral-at-Me;  Kenichi Endo Book 2021 The Editor(s)
描述This book describes novel synthetic methodologies for two kinds of structurally elaborate metal complexes: a heterometallic complex and a tetrahedral chiral-at-metal complex. The book provides the tools and inspiration to chemists for development of metal complexes with wide structural diversity than had previously been possible. For each of the two topics, existing synthetic methods for similar compounds are discussed first, and then new strategies are presented, followed by the demonstration of the synthesis of novel compounds supported by experimental results..Both of the final products in this research, a Co–Ni heterometallic complex covered in the first topic and a tetrahedral chiral-at-metal complex in the second one are difficult to obtain by using common synthetic methods for thermodynamic reasons. This research achieved highly selective syntheses of these compounds using newly designed strategies that enable precise kinetic control. Suchan approach will be useful for synthesizing other new metal complexes..Since the last century, organic chemistry has flourished with the development of a variety of synthetic techniques that make precise kinetic control possible. Coordinati
出版日期Book 2021
关键词Chiral-at-metal Complex; Heterometallic Complex; Selective Synthesis; Metal Complex; Coordination Chemis
版次1
doihttps://doi.org/10.1007/978-981-16-1163-6
isbn_softcover978-981-16-1165-0
isbn_ebook978-981-16-1163-6Series ISSN 2190-5053 Series E-ISSN 2190-5061
issn_series 2190-5053
copyrightThe Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapor
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发表于 2025-3-21 21:09:14 | 显示全部楼层
Heterometallic CoIINi 3 II Complex,tal ions. However, most examples previously reported depend on one-step methods or are based only on 4d- or 5d-metal ions. Here, a new strategy toward an otherwise difficult arrangement of different 3d-metal ions has been achieved by kinetically controlled multistep sequence: site-selective redox sw
发表于 2025-3-22 02:04:16 | 显示全部楼层
Tetrahedral Chiral-at-Metal ZnII Complex,ttractive because it can act as enantioselective catalyst, chiroptical material, and so on in the absence of chiral ligands. However, there are two problems in chiral-at-metal complexes without chiral ligands. Firstly, pure enantiomers are usually obtained only by separation, and enantioselective sy
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an Union, Portugal, and Spain share a border that is relatively porous and easily traversed. Nevertheless, movements across the . (a local term shared by Galician and Portuguese languages for the division between northern Portugal and southern Galicia) have not always been so fluid and easily traver
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Kenichi Endoe reached its end. Nevertheless, the dramatic outbreak of the 2008 economic crisis has reactivated outward migration, now in much more complex forms. The more recent flows of Galician emigration have been fed by return trajectories of previous immigrants, some of whom have become naturalized Spanish
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asic elements of the Galician village—from landholding arrangements and the layout of buildings to the categories of inhabitants and relations among them—all remained fundamentally as they had taken shape during the previous centuries of serfdom. Even though the national movement did not, and could
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