书目名称 | Kinetically Controlled Stepwise Syntheses of a Heterometallic Complex and a Tetrahedral Chiral-at-Me |
编辑 | Kenichi Endo |
视频video | |
概述 | Nominated as an outstanding Ph.D. thesis by the University of Tokyo.Presents synthetic strategies for metal complexes in detail.Introduces unique techniques to distinguish similar complexes |
丛书名称 | Springer Theses |
图书封面 |  |
描述 | This book describes novel synthetic methodologies for two kinds of structurally elaborate metal complexes: a heterometallic complex and a tetrahedral chiral-at-metal complex. The book provides the tools and inspiration to chemists for development of metal complexes with wide structural diversity than had previously been possible. For each of the two topics, existing synthetic methods for similar compounds are discussed first, and then new strategies are presented, followed by the demonstration of the synthesis of novel compounds supported by experimental results..Both of the final products in this research, a Co–Ni heterometallic complex covered in the first topic and a tetrahedral chiral-at-metal complex in the second one are difficult to obtain by using common synthetic methods for thermodynamic reasons. This research achieved highly selective syntheses of these compounds using newly designed strategies that enable precise kinetic control. Suchan approach will be useful for synthesizing other new metal complexes..Since the last century, organic chemistry has flourished with the development of a variety of synthetic techniques that make precise kinetic control possible. Coordinati |
出版日期 | Book 2021 |
关键词 | Chiral-at-metal Complex; Heterometallic Complex; Selective Synthesis; Metal Complex; Coordination Chemis |
版次 | 1 |
doi | https://doi.org/10.1007/978-981-16-1163-6 |
isbn_softcover | 978-981-16-1165-0 |
isbn_ebook | 978-981-16-1163-6Series ISSN 2190-5053 Series E-ISSN 2190-5061 |
issn_series | 2190-5053 |
copyright | The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapor |