Titlebook: Iron Catalysis II; Eike Bauer Book 2015 Springer International Publishing Switzerland 2015 Carbon-Nitrogen Bond Formation.Carbon-Phosphoru

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Iron-Catalyzed Cross-Dehydrogenative-Coupling Reactions, the perspective of atom economy. A variety of carbon–carbon bond-forming reactions utilizing various coupling partners are known today. Iron-catalyzed organic syntheses have attracted considerable attention because iron is an abundant, inexpensive, and environmentally benign metal. This chapter sum

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,Iron-Catalyzed Carbon–Nitrogen, Carbon–Phosphorus, and Carbon–Sulfur Bond Formation and Cyclizationnes, cross-coupling reactions, cycloadditions, tandem or consecutive reactions, or C–H functionalization is an attractive strategy in organic synthesis and is an intensive research area. Many organometallic species, more specifically palladium, nickel, and rhodium complexes, have paved the way to us

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High-Valent Iron in Biomimetic Alkane Oxidation Catalysis,e nature of which has been under discussion in the chemical literature for more than a century. Recent advances in the design and development of molecular iron-based oxidation catalysts and their mechanistic understanding are summarised in this chapter, in particular iron complexes featuring tetrade

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Iron-Catalyzed Oligomerization and Polymerization Reactions,ety of catalytic systems for polymerization and oligomerization of unsaturated hydrocarbons. Over the last 15 years, the development of mid- to late transition metal catalysts has provided significant advances in this area. The availability of iron combined with its low environmental impact and its

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Enantioselective Iron Catalysts,ubiquitous, inexpensive, and environmentally benign metal. It has been documented that various chiral iron complexes can be used in many reactions such as oxidation, cyclopropanation, hydrogenation, hydrosilylation, and alkane hydroxylation. This chapter summarizes recent developments, mainly from 2

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Molecular Iron-Based Oxidants and Their Stoichiometric Reactions,erted to catalytic protocols, they hold great promise for the development of greener methods for this particularly messy class of reaction. For application in organic synthesis, the biggest question is: How selective can the reactions be? The supporting ligands in these compounds are crucial for tun

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Book 2015anometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad rang

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Iron-Catalyzed Cross-Dehydrogenative-Coupling Reactions,d organic syntheses have attracted considerable attention because iron is an abundant, inexpensive, and environmentally benign metal. This chapter summarizes the development of iron-catalyzed CDC reactions, the reaction mechanism, and the role of the Fe species in the catalytic cycle in the period from 2007 to 2014.

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