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Titlebook: Integration of Fundamental Polymer Science and Technology—2; P. J. Lemstra,L. A. Kleintjens Book 1988 Elsevier Applied Science Publishers

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Anionic Ring-Opening Polymerization of Carbonates and Formation of Blockcopolymers to result in high molecular weight polymers. Under suitable conditions, a ring-chain equilibrium is established, i.e., beside acyclic polymers a homologous series of cyclic oligomers is obtained. The different cyclic carbonates discussed open a variety of secondary reactions, in particular cross-li
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Preparation of Block Copoly(Arylene Sulphides) Utilising Preferential Polymer Formation in Polymerisof poly(1,4-phenylene sulphide)(A) and poly(2-methyl-1,4-phenylene sulphide)(B) from bis-(4-bromophenyl)sulphone by sequential reaction with copper (I) 4-bromo-2-methylthiophenoxide and copper (I) 4-bromothiophenoxide. The materials produced have been characterised by IR/NMR spectroscopy, elemental
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Stabilization of Poly(ethylene Terephthalate) (PET) against Hydrolysis by Carboxylic End Group Cappia polycarbodiimide and a bisepoxy compound have been used. For a proper stabilization an excess of polycarbodiimide should be added, so that newly formed carboxylic end groups are also removed. The bisepoxide used shows a relatively low reactivity towards carboxylic end groups. Sodium benzoate and t
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Graft Copolymerization of Styrene-Maleic Anhydride and CIS-Polybutadiener complexes in the propagation reactions has been confirmed. Attentions were paid to the effect of reaction parameters (agitation speed, polymerization temperature, initiator concentration, rubber content, MA content) on phase inversion, and influence of addition of MA to polymerization system on st
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