Titlebook: Inorganic Stereochemistry; David L. Kepert Book 1982 Springer-Verlag Berlin, Heidelberg 1982 Anorganische Chemie.Stereochemie.chemistry.co

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Seven-Coordinate Compounds Containing Chelate Groups,The potential energy surfaces for [M(bidentate)(unidentate).] are complex, and contain a number of minima. A summary of the more important stereochemistries, corresponding to calculated potential energy minima, is given in Fig. 11.1.

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Ten-Coordinate Compounds,There is as yet no structurally characterized ten-coordinate compound containing ten unidentate ligands. Nevertheless the geometry of these hypothetical compounds is a useful introduction to the stereochemistry of known ten-coordinate complexes such as [M(bidentate ligand).].

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