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Titlebook: Infrared Spectroscopy of Molecular Clusters; An Introduction to I Martina Havenith Book 2002 Springer-Verlag Berlin Heidelberg 2002 cluster

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发表于 2025-3-21 19:13:18 | 显示全部楼层 |阅读模式
书目名称Infrared Spectroscopy of Molecular Clusters
副标题An Introduction to I
编辑Martina Havenith
视频video
概述Up-to-date overview.Springer Tracts in Modern Physics is also available online via the LINK Service: http://link.springer.de/series/stmp.Includes supplementary material:
丛书名称Springer Tracts in Modern Physics
图书封面Titlebook: Infrared Spectroscopy of Molecular Clusters; An Introduction to I Martina Havenith Book 2002 Springer-Verlag Berlin Heidelberg 2002 cluster
描述This book is intended to give an introduction to intermolecular forces from an experimental point of view. Within the last 10 years the interest has turned more and more into an understanding of the weak, but important, int- molecular forces. New experimental techniques have been developed which have helped to gain more insight into this interesting topic. This book is intended as an introduction for graduate students who are familiar with the main concepts of n~olecular spectroscopy. Special emphasis will be laid on the theoretical concepts. After a detailed description of experimental techniques, the results for two prototype systems which have been the subject of several studies in the literature within recent years will be presented. Ar-CO is becoming the most extensively studied van der Waals complex, theoretically and experimentally. Nevertheless, this example shows that even though the theory has greatly improved and has helped us to improve our knowledge of intermolecular forces, even for relatively simple cases the theory car1 still fall short of an accurate description. For a long time (NH3)2 was considered as a prototype for hydrogen bo- ing. However, subsequent experime
出版日期Book 2002
关键词cluster; molecule; spectroscopy
版次1
doihttps://doi.org/10.1007/3-540-45457-8
isbn_softcover978-3-662-14648-4
isbn_ebook978-3-540-45457-1Series ISSN 0081-3869 Series E-ISSN 1615-0430
issn_series 0081-3869
copyrightSpringer-Verlag Berlin Heidelberg 2002
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发表于 2025-3-22 00:11:06 | 显示全部楼层
Intermolecular Interactions,uantitative description of intermolecular interactions. Textbooks discussing this subject include [126, 165, 185]. Later on I shall give an overview of the work of other groups, related to semiempirical potentials.
发表于 2025-3-22 02:15:57 | 显示全部楼层
Semiempirical Potentials,or of the attractive interactions can be represented as . . (. ≥ 3), which decreases rather slowly compared with the repulsive contribution, which decreases rapidly, as exp(−.). For large . values, the potential will therefore follow an . . dependence; for example, the interaction between two non-po
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Infrared Spectroscopy of Complexes,n microwave and infrared spectroscopy of weakly bound complexes [109]. I shall therefore give only a short summary here. Infrared spectroscopy is a well-established technique for the investigation of stable molecules. Infrared spectroscopy started in the 1930s (see [82]) and yielded a wealth of info
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The Diode Laser Spectrometer,e of great commercial interest. Owing to their efficiency and compactness, they have replaced gas lasers in some areas. While most commercial diode lasers work in the red spectral region (ca. 635 nm), special diodes are available in the infrared and, more recently, in the green and blue regions (e.g
发表于 2025-3-22 17:05:42 | 显示全部楼层
The CO Sideband Spectrometer, the resolution of lead salt diode lasers (50-100 MHz). However, the use of nonlinear frequency mixing of a finely tunable CO laser with microwave radiation allows the generation of narrow (< 300 kHz) IR radiation which can be used for high-resolution spectroscopy of complexes. The overall experimen
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,(NH3)2 — a Prototype of Hydrogen Bonding?,a hydrogen atom attached to an electronegative atom, such as oxygen, a halogen or nitrogen, and another electronegative atom. The strength of this interaction clearly exceeds the values for the normal van der Waals interaction. Binding energies for hydrogen bonding are typically on the order of 1000
发表于 2025-3-23 05:58:09 | 显示全部楼层
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