Titlebook: Hydrofunctionalization; Valentine P. Ananikov,Masato Tanaka Book 2013 Springer-Verlag Berlin Heidelberg 2013 Addition to unsaturated molec

咽下

,Groups 9 and 10 Metals-Catalyzed O–H Bond Addition to Unsaturated Molecules,Progress in the field of inter- and intramolecular additions of oxygen nucleophiles (water, alcohols, phenols, and carboxylic acids) to alkenes, allenes, alkynes, and nitriles catalyzed by Co, Rh, Ir, Ni, Pd, and Pt is critically reviewed.

骑师

superfluous

insert

决定性

显而易见

,Alkyne and Alkene Insertion into Metal–Heteroatom and Metal–Hydrogen Bonds: The Key Stages of Hydroal of multiple bonds activation and insertion in the metal complexes is far from being fully explored. The key factors determining insertion pathways into metal–heteroatom vs. metal–hydrogen bonds and the influence on regioselectivity of the insertion remain to be revealed in nearest future.

舰旗

,Group 8 Metals-Catalyzed O–H Bond Addition to Unsaturated Molecules,ons to alkenes are still scarce with these metals and the use of iron catalysts is limited, the main part of the chapter is dedicated to addition of carbamates, carboxylic acids, alcohols and water to triple bonds with ruthenium catalysts.

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维持

Late Transition Metal-Catalyzed Hydroamination,achieved. The reaction pathways strongly depend on the choice of metal complexes, substrates, and reaction conditions. This chapter is organized primarily based on the difference in the mechanisms of hydroamination reactions, and in the scope section concise summary of the hydroamination reaction is shown.

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