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Titlebook: Hydroboration and Organic Synthesis; 9-Borabicyclo [3.3.1 Ranjit S. Dhillon Book 2007 Springer-Verlag Berlin Heidelberg 2007 Medicinal Chem

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Synthesis of Nitriles,h yield (Eq. 10.1). The reaction intermediate undergoes protonolysis readily and without adding ethanol or other protonolyzing agent as required, for example, in the synthesis of ketones under similar conditions.
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,Synthesis of (,)-β,γ-Unsaturated Amides, not stereodefined, and others require the use of valuable noble metal catalysts and carbon monoxide. However, it is possible to synthesize in a stereodefined manner (.)-β,γ-unsaturated amides from .-9-alkenyl-9-BBN with .-dialkyl(dimethylsulfuranylidene)acetamide [4] with a two-carbon increase. .,-
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Synthesis of Dialkylsulfides,s for radical reactions [2, 3]. It is reported [4] that in the presence of a catalytic amount of 9-BBN or .-hexyl-9-BBN, or to some extent .-methoxy-9-BBN, initiates the radical addition of alkanethiols to alkenes under very mild conditions to provide the corresponding dialkylsulfides almost in quan
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