Titlebook: Hydroboration and Organic Synthesis; 9-Borabicyclo [3.3.1 Ranjit S. Dhillon Book 2007 Springer-Verlag Berlin Heidelberg 2007 Medicinal Chem

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iety of organic compounds required for industry. Consequently, this vast field in the form of a book will be helpful to synthetic organic chemists for easy access to literature, required for chemical transformations..978-3-642-08034-0978-3-540-49076-0

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Introduction,istry, and the hydroboration reactions of major significance in synthetic organic chemistry have been reviewed [1–15]. Selective hydroboration with various hydroborating agents and their application in organic synthesis has also been reviewed [16].

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Synthesis of Halides,when 1 equiv of sodium hydroxide or sodium methoxide in methanol is added to a mixture of 1 mol of organoborane and 1 mol of iodine. The reaction becomes instantaneous and affords the corresponding alkyl halides. A second mole of iodine and base react similarly (Eq. 13.1) [4–6], but the third alkyl resists the reaction under these conditions.

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s book will fill the gap.Includes supplementary material: .9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration re

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Book 2007he reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-N, C-S, C-halogen, C-metal and above all C-C bonds. In addition, the suitable substituted / unsaturated R of B-R-9-BBN can be utilized to produce die

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Kinetic Studies, predicting the selective hydroboration of C=C or C≡C or their functionalized derivatives. 9-BBN has proven to be the best candidate for the investigation of mechanism and kinetics of hydroboration because:

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Synthesis of Dialkylsulfides,oxides or azo compounds, by UV radiations, or by radiolysis [5]. The reaction initiated by 9-BBN is completely inhibited in the presence of galvinoxyl, a radical trapping agent. This confirms that 9-BBN participates in the initiation of radical addition (Table 14.1) [4].

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Book 2007els-Alder and Suzuki reactions have expanded the utility of 9-BBN for the synthesis of a variety of organic compounds required for industry. Consequently, this vast field in the form of a book will be helpful to synthetic organic chemists for easy access to literature, required for chemical transformations..

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