Titlebook: Homogeneous Hydrogenation in Organic Chemistry; F. J. McQuillin Book 1976 D. Reidel Publishing Company, Dordrecht, Holland 1976 Chemical r

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压倒性胜利

EWE

0920-4652 and predictable level of stereoselectivity. In the light of much accumulated ex­ perience within organic chemistry it is usually possible to assess the likeli­ hood of alternative reaction pathways at least qualitatively. However, well based expectations can be falsified, and the experiments direct

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Catalytic Activation of Alkane Carbon-Hydrogen Bonds,ability and lack . of polarisability of the carbon-hydrogen bond. Despite these effective stabilising factors, however, conditions have in fact been established for activation of the carbon — hydrogen bond for catalytic .H—.H exchange in alkanes and cycloalkanes.

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Decrepit

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Hydrogenolysis of Cyclopropanes,only a limited extent. Using RhCl(PPh.). in benzene, hydrogenolysis has been observed in the examples (l)–(6), the extent of hydrogenolysis and the nature of the hydrogenolysis products being as indicated [1].

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F. J. McQuillinicht ertragen, sein armes Gehirn soll erdrückt, sein Beutel soll völlig geleert werden. Mitten in aller Herrlichkeit fängt er an zu seufzen: wollte Gott, ich säße still im Wald, das wäre für Geist und Körper besser! Ja, es wäre schöner; aber lehrreicher und darum nützlicher ist es doch am Ende, hier