Titlebook: Homogeneous Catalysis with Metal Phosphine Complexes; Louis H. Pignolet Book 1983 Springer Science+Business Media New York 1983 catalysis.

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Homogeneous Catalysis of Oxidation Reactions Using Phosphine Complexes,on, and biological oxidation processes are fundamental to life and ecology. From an industrial viewpoint, oxidation reactions occupy a pivotal role in the conversion of hydrocarbons into required products, and indeed it has been estimated that over 50% of such processes involve hydrocarbon oxidation

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Mechanistic Studies of Catalytic Reactions Using Spectroscopic and Kinetic Techniques,w they operate. It is these systems that form the focus of this chapter. For more general reviews the reader is referred to some recent books,. which also discuss the special electronic properties of transition metals which are in part responsible for their catalytic behavior.†

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Book 1983 necessary for catalytic reactivity and selectivity. This point will be emphasized throughout the book. Thus the stage is set for a comprehensive be treatment of the many ways in which phosphine catalyst systems can designed, synthesized, and studied.

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s that are necessary for catalytic reactivity and selectivity. This point will be emphasized throughout the book. Thus the stage is set for a comprehensive be treatment of the many ways in which phosphine catalyst systems can designed, synthesized, and studied.978-1-4613-3625-9978-1-4613-3623-5

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Structurally Characterized Transition-Metal Phosphine Complexes of Relevance to Catalytic Reactionsthe analogue is indeed a good model for the temporal species in the catalytic reaction. A second answer is that such structural information is an aid to the formulation of reaction schemes, some of which are based on minimal data. In such schemes there frequently are proposed intermediates of new or

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Asymmetric Hydrogenation Reactions Using Chiral Diphosphine Complexes of Rhodium,l center in the catalyst which controls asymmetric induction is three bonds removed from the metal and spatially remote from it. This leads to an immediate suspicion that the chelate ring is in some way controlling the orientation of the P-Ph rings, which in turn determines the stereochemical outcom