Titlebook: Homogeneous Catalysis with Metal Phosphine Complexes; Louis H. Pignolet Book 1983 Springer Science+Business Media New York 1983 catalysis.

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Binuclear, Phosphine-Bridged Complexes: Progress and Prospects,neous reactions. Recently, binuclear metal complexes, particularly those with bridging phosphine ligands, have begun to attract interest because of their potential as catalysts and because of their novel structural and reactive features. The interest in binuclear complexes arises because of anticipa

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Functionalized Tertiary Phosphines and Related Ligands in Organometallic Coordination Chemistry andst straightforward way to affect the chemical behavior of a given metal ion is through changes in its ligands. It is well recognized that changes within the first coordination sphere of a metal ion can have a relatively dramatic impact on the properties of the entire complex. On the other hand, modi

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Polydentate Ligands and Their Effects on Catalysis,ine complexes display a tremendous range of coordination numbers, stereochemistries, catalytic properties, and selectivities. The effects can also be “fine-tuned” by purposeful variation of the steric and electronic effects of the substituent groups on phosphorus and from synthesis of polydentate ph

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Cationic Rhodium and Iridium Complexes in Catalysis,. In this review, we will first survey the effects of net charget on the reactivity of metal complexes in general, before going on to the specific case of cationic complexes of rhodium and iridium in catalysis. We will not discuss work bearing on asymmetric hydrogenation, since this is covered in Ch

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Decarbonylation Reactions Using Transition Metal Complexes,h several methods not utilizing transition metals are known. (including various deformylation reactions and thermal and photochemical decarbonylations), they are not general and not usually applicable under mild conditions where undesirable side reactions are minimized..