Titlebook: Highlights in Solute-Solvent Interactions; Wolfgang Linert Book 2002 Springer-Verlag Wien 2002 Inorganic Chemistry.liquid.organic chemistr

Expostulate

Recent Advances in the Description of the Structure of Water, the Hydrophobic Effect, and the Like-Following a critical survey of the vast recent literature, the state of the art may be summarized as follows:

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Ionic Solvation in Aqueous and Nonaqueous Solutions,ons are discussed. An emphasis is placed on ionic solvation in nonaqueous mixed solvents in which preferential solvation of ions takes place. A new parameter for expressing the degree of preferential solvation of an ion is proposed.

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The Solvent-Like Nature of Silica Particles in Organic Solvents,meters for the various solid acids are analyzed by means of Fe(phen).(CN).(cis-dicyano-bis-(1,10)-phenanthrolineiron(II), ., . ketone (4,4’-bis-(dimethylamino)-benzophenone, ., and two hydrophilic derivatives of .(dimethylamino)-4’-(di-2-hydroxyethyl)-amino-benzophenone. and 4,4’-bis(di-(2-hydroxyet

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Preferential Solvation in Mixed Solvents X. Completely Miscible Aqueous Co-Solvent Binary Mixtures preferential solvation parameters derived from them are presented. Also presented are these latter quantities for 15 additional such mixtures, for which the volume correction has not been applied previously. The self-interaction of the water, the mutual interaction of the water and the co-solvent,

WAG

Phase Transitions and Critical Behaviour of Binary Liquid Mixtures,bution we restrict ourselves to so-called binary symmetric mixtures, i.e. where like-particle interactions are equal (..(.) = Φ.(.)), whereas the interactions between unlike fluid particles differ from those of likes ones (..(.)≠..(.)). Using both the simple mean spherical approximation and the more

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Solvent Effects on Ion-Pair Distribution and Dimerization of Tetraalkylammonium Salts,nic solvents was studied at 25.0°C. The distribution data were analyzed by taking into consideration the distribution of ion pairs, ...X., and the dimerization of the ion pairs, (...X.)., in the organic phase. The ion-pair, distribution constant, .., increases with increasing chain length of the tet

Factual

e history strategies of living organisms. Thereafter, adaptive strategies have been viewed as the outcome of various co-adapted features which can be exemplified not only on demographic but also on physiological and behavioural grounds (e.g. Siepel 1994). In this chapter, the focus is on the respira