Titlebook: Generalized Statistical Thermodynamics; Thermodynamics of Pr Themis Matsoukas Book 2018 Springer Nature Switzerland AG 2018 statistical the

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The Bicomponent Ensemble,ed this to the partitioning of a set of extensive variables, .., .., ⋯ into . clusters. .. may represent energy, volume, or any other extensive attribute that is distributed. A special case is when this attribute refers to a . that we recognize as a .. A population that contains two or more componen

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Generalized Thermodynamics, fixed zeroth and first order moments. Thermodynamics arises naturally in this ensemble when . and . become very large. In this chapter we will reformulate the theory on a mathematical basis that is more abstract and also more general. The key idea is as follows. If we obtain a sample from a given d

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Contemporary Topics in Polymer Sciencerely new viewpoint. Starting with Shannon’s work on information theory and Jaynes’s formulation of maximum entropy has now escaped from the realm of physics to invade other fields. In this chapter we review the evolution of ideas on entropy, from the classical view, to Gibbs, Shannon, and Jaynes, an

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https://doi.org/10.1007/978-3-030-11860-0re the existence of the most probable distribution and identify the . as a phase that is distinct from the ., a stable population of dispersed clusters. We discuss two mathematical models that give rise to a giant cluster and solve them analytically. A kinetic model of gelation with a closer connect

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