Titlebook: Epoxidations and Hydroperoxidations of α,β-Unsaturated Ketones; An Approach through Corinna Reisinger Book 2012 Springer-Verlag Berlin Hei

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Results and Discussion,Simple cyclic enones have generally been omitted within the vast majority of studies on the asymmetric epoxidation of α,β-unsaturated ketones. Thus, we decided to focus on these challenging cyclic substrates as a departure point before extending the methodology to different types of α,β-unsaturated ketones.

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2190-5053 are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date..978-3-642-43533-1978-3-642-28118-1Series ISSN 2190-5053 Series E-ISSN 2190-5061

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Epoxidations and Hydroperoxidations of α,β-Unsaturated KetonesAn Approach through

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2190-5053 hemistry.This work could lead to numerous commercial applica.Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic α,β-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as

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John R. Ferraro,Joseph S. Ziomekalyzed by a chiral imidazolidinone salt by MacMillan et al. [2] have raised awareness of the potential of purely organic molecules as efficient catalysts for a variety of asymmetric transformations and brought to life the term “organocatalysis” to address this research field (Scheme 2.1).