Titlebook: Energetics of Organometallic Species; J. A. Martinho Simões Book 1992 Springer Science+Business Media Dordrecht 1992 Silane.chemistry.comb

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Book 1992rrespond to the seventeen lectures delivered at the NATO ASI Energetics of Organometallic Species (Curia, Portugal, September 1991), plus three other invited contributions from participants of that summer school. These papers reflect a variety of research interests, and discuss results obtained with

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Historical Perspective of Organometallic Thermochemistry,nterest of thermochemists. Organometallic compounds were then of minor interest, and few such data had been measured. The development later of rotating bomb calorimetry, the use of combustion aids, advances in solution reaction calorimetry, and in particular, the adaptation of the Calvet twin-microc

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The Role of Bond Energies in Hydrocarbon Activation by Transition Metal Centers,centers. Advances have been made in both understanding the interactions of hydrocarbons with metals and in the energetics of these interactions. We have examined reactions of a series of arenes with (C.Me.) Rh(PMe.) PhH and begun to map out the kinetic and thermodynamic preferences for arene coordin

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Rh-C Bond Dissociation Enthalpies for Organometallic Derivatives of Rhodium Porphyrins,s are used in deriving estimates of Rh—C bond dissociation enthalpies. Maximum Rh—C D values occur for the methyl and formyl derivatives (D(Rh-CH3~242 kJ mol. (58 kcal mol.); D(Rh-CHO=249 kJ mol. (59 kcal mol.)) where the steric demands of the organic fragments are minimized.

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Solution Thermochemistry of Organometallic Compounds Using Photoacoustic Calorimetry: Enthalpies ofof the enthalpy of CO substitution on M(CO). (M = Cr, Mo, W) by heptane, CO substitution on Cr(CO). by amines (piperidine, .-butylamine, di-.-butylamine, tri-.-butylamine) and by weakly coordinating solvents (alkane, aromatic, and chlorocarbon solvents), and CO substitution on various metal carbonyl