Titlebook: Elemental Sulfur and Sulfur-Rich Compounds II; Ralf Steudel Book 2003 Springer-Verlag Berlin Heidelberg 2003 Sulfur.chemistry.inorganic ch

决定性

伦理学

Sulfur-Rich Oxides S,O and S,O,(,>1),gen atoms are present as part of a sulfoxide group. In some cases adducts with Lewis acids have been prepared, e.g., S.OSbCl., (S.O).SnCl., and S.O.(SbCl.).. The preparation, thermal stabilities, molecular structures, spectra, and reactions are described.

粘连

Inorganic Polysulfides S,, and Radical Anions S,,,ions, as well as their solid state structures, vibrational spectra and their behavior in aqueous and non-aqueous solutions. In addition, the highly colored and reactive radical anions S..with. = 2, 3, and 6 are discussed, some of which exist in equilibrium with the corresponding diamagnetic dianions.

Free-Radical

Inculcate

Über das Schreiben von Ethnographie the metal and its oxidation number but to a large extent also on the other ligands present and in particular on their bulkiness. This review describes the progress made in the area of polysulfido complexes with regard of their synthesis, structures and reactions.

single

沉着

Quantum-Chemical Calculations of Sulfur-Rich Compounds,lfur clusters and their cations, anions and protonated forms, as well as sulfur-sulfur three-electron bonded systems. Special emphasis is placed on their roles in understanding the molecular structures, thermochemical properties, chemical bonding and reaction mechanisms of this class of compounds.

Polydipsia

Molecular Spectra of Sulfur Molecules and Solid Sulfur Allotropes,hapter the vibrational, UV-Vis and mass spectra of sulfur molecules with between 2 and 20 atoms are critically reviewed together with the spectra of liquid sulfur and of solid allotropes including polymeric and high-pressure phases. In particular, low temperature Raman spectroscopy is a suitable tec

PALSY

Inorganic Polysulfanes H,S, with, > 1,es are the parent compounds of numerous derivatives with either organic or inorganic substituents. In this chapter the preparation, structures, physical and chemical properties as well as the spectra of the sulfanes with ≥2 sulfur atoms are reviewed. In the literature these species are termed either

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