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Titlebook: Electrochemical Processes in Fuel Cells; Manfred W. Breiter Book 1969 Springer-Verlag New York Inc. 1969 Ion.Oxidation.chemistry.electroca

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书目名称Electrochemical Processes in Fuel Cells
编辑Manfred W. Breiter
视频video
丛书名称Anorganische und allgemeine Chemie in Einzeldarstellungen
图书封面Titlebook: Electrochemical Processes in Fuel Cells;  Manfred W. Breiter Book 1969 Springer-Verlag New York Inc. 1969 Ion.Oxidation.chemistry.electroca
描述The necessity for a better understanding of the basic processes that determine the operation of fuel cells became evident during the devel­ opment of practical units in the last three decades. The search for efficient electrocatalysts in low-temperature fuel cells intensified the general study of the nature and the role of the electrode material. Re­ search on the complex mechanisms of the anodic oxidation of different fuels and of the reduction of molecular oxygen on solid electrodes was stimulated, and the strong influence of adsorbed species on the electrode reaction in question was investigated. Suitable electrolytes had to be found for the high-temperature fuel cells. The use of electrodes with large internal surface lead to the development of models of porous electrode. structures and to the mathematical analysis of the operation of these models under certain conditions. While the chapters I to III introduce the reader to the general field offuel cells, the progress made in the understanding of the basic problems in the electrochemistry of fuel cells since the end of the second world war is reviewed in chapters IV to XVI of this monograph. In contrast, the technological aspec
出版日期Book 1969
关键词Ion; Oxidation; chemistry; electrocatalyst; electrochemistry; fuel cell
版次1
doihttps://doi.org/10.1007/978-3-642-46155-2
isbn_softcover978-3-642-46157-6
isbn_ebook978-3-642-46155-2Series ISSN 0066-4553
issn_series 0066-4553
copyrightSpringer-Verlag New York Inc. 1969
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Mass Transport Processes,actions at the anode or cathode have to be transported to the respective electrode surfaces. The basic concepts of transport processes are briefly outlined in this chapter. The reader is referred for a comprehensive treatment to the book on physicochemical hydrodynamics by . [1]. Phenomena resulting
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Anodic Oxidation of Molecular Hydrogen at Low Temperatures,ient resistance to corrosion in acid media and are good electrocatalysts at the same time. The mechanism of the anodic H. oxidation is discussed for noble metals and their alloys in section 1 of this chapter. The conclusions derived for acid solutions can be easily transferred to alkaline electrolyt
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Oxygen Layers on Different Materials and Inhibition of Fuel Oxidations,VI and VII. The word “oxygen layer” is used in a general sense here to denote chemisorbed layers of OH. and O. as well as hydroxide layers and oxide layers. The potential region in which the oxygen layers are formed and reduced on platinum metals was called “oxygen region”. Details about the formati
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Adsorption of Carbonaceous Species on Platinum Metals,s play an important role in our understanding of electrocatalysis. The techniques for their study, their properties and coverage of the surface under different conditions are discussed in this chapter. The role of adsorbed species in the oxidation of various fuels is dealt with in chapter X.
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The Oxygen Electrode at Low Temperatures, in fuel cells. The use of air is preferable for economic reasons. Platinum metals and alloys of platinum metals are electrocatalysts for acid and alkaline electrolytes. Silver, silver alloys, nickel, carbon, and intermetallic compounds represent less expensive electrocatalysts for the oxygen electr
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Processes in Fuel Cells with Solid Electrolytes,2], and . [3]. Since the problem of electrocatalysis is not serious [4,5] at temperatures around 1000°C, the main emphasis has been on the improvement of solid electrolytes and on the development of suitable cell designs in recent years.
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