书目名称 | Dynamical Decoupling in Distance Measurements by Double Electron-Electron Resonance |
编辑 | Janne Marie Soetbeer |
视频video | |
概述 | Study in Natural Science.Includes supplementary material: |
丛书名称 | BestMasters |
图书封面 |  |
描述 | Janne Marie Soetbeer determines the optimal dynamical decoupling (DD) scheme for efficient reduction of electron spin coherence loss in model systems for spin labelled biomolecules depending on their particular relaxation behavior. Extending the n.th. order DD scheme to double electron-electron resonance (DEER) experiments require the addition of multiple pump pulses for ≠ 1. Incomplete excitation of pump spin packets introduce signal artefacts which are minimized by pump pulse optimization including linear-chirp and asymmetric hyperbolic secant pulses. Prolonging the dipolar evolution time with decreased signal artefact allows to extent the measurable interspin distances in biomolecules which were otherwise not accessible due to spin echo relaxation. |
出版日期 | Book 2016 |
关键词 | DEER; Relaxation or Electron Spin Relaxation; Carr-Purcell; Uhrig; Adiabatic pulse; PELDOR |
版次 | 1 |
doi | https://doi.org/10.1007/978-3-658-14670-2 |
isbn_softcover | 978-3-658-14669-6 |
isbn_ebook | 978-3-658-14670-2Series ISSN 2625-3577 Series E-ISSN 2625-3615 |
issn_series | 2625-3577 |
copyright | The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Fachmedien Wies |