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Titlebook: Developments in Polymer Stabilisation—8; Gerald Scott (Professor of Polymer Science) Book 1987 Elsevier Applied Science Publishers Ltd 198

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书目名称Developments in Polymer Stabilisation—8
编辑Gerald Scott (Professor of Polymer Science)
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图书封面Titlebook: Developments in Polymer Stabilisation—8;  Gerald Scott (Professor of Polymer Science) Book 1987 Elsevier Applied Science Publishers Ltd 198
描述The purpose of the present series of publications is two-fold. In the first place it is intended to review progress in the development of practical stabilising systems for a wide range of polymers and applications. A complementary and ultimately more important objec­ tive is to accommodate these practical developments within the framework of antioxidant theory, since there can be little question that further major advances in the practice of stabilisation technology will only be possible on the basis of a firm mechanistic foundation. Research into the role of ‘stable‘ free radicals as antioxidants and stabilisers for polymers has intensified in recent years. Nitroxyl radicals (nitroxides) were the earliest long-lived radicals to be investi­ gated in detail and Maslov and Zaikov review the developments that have taken place in understanding their reaction mechanisms from the time when they were first investigated in liquid hydrocarbon systems to the present day when their outstanding performance as light stabilisers has been the object of much scientific research. Although some features of their reactivity remain obscure, the authors approach the problem kinetically and indicate the
出版日期Book 1987
关键词Polyolefin; development; foundation; hydrogen; liquid; mechanism; oxides; polymer; reaction; research; resonan
版次1
doihttps://doi.org/10.1007/978-94-009-3429-0
isbn_softcover978-94-010-8034-7
isbn_ebook978-94-009-3429-0
copyrightElsevier Applied Science Publishers Ltd 1987
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978-94-010-8034-7Elsevier Applied Science Publishers Ltd 1987
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Image Storage and Communicationers characterizing the efficiency of nitroxyl radicals as inhibitors are given and data on the coefficients of inhibition and regeneration of nitroxyl radicals are also presented. The possibility of nitroxyls taking part in chain initiation reactions is considered and criteria for using nitroxyl rad
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General Physics Principles in Brachytherapys been studied by hydrogen or electron transfer to free and chelated transition metals coordinated with RO., RO. and . radicals. Spin density distribution effects, regulated by electron push-pull substituents, steric effects and the presence of transition metals in different oxidation states, condit
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Handbook of Image-Guided Brachytherapyant to extraction and volatilisation. Two routes to obtain polyolefin-bound stabilisers are described in this chapter, both involving polyolefin grafting. In the first method, polyolefins are grafted with reactive stabilisers—bifunctional compounds containing a polymerisable group and an antioxidant
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https://doi.org/10.1007/978-3-030-68165-4scussed. The evidence suggests that the need for substantive antioxidants and stabilisers in a range of polymer substrates can be satisfied by adduct concentrates in a small number of polymers and that the adducts can be used in the same way as conventional additives. The future potential for polyme
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https://doi.org/10.1007/978-3-030-68165-4n some cases be of no help in determining the useful life-time of the plastics end-product. This chapter critically examines the accelerated testing procedures used to assess the stability of plastics to thermo- oxidation and photo-oxidation..Thermal analysis techniques such as DSC are discussed in
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