Titlebook: Development of a New Heterocycle-Forming Reaction and Kinetic Resolution with N-Heterocyclic Carbene; Yinli Wang Book 2019 Springer Nature

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Die Zeit als Tatbestandsmerkmalichiometric amount of NHC. This reaction proceeded in a.-Umpolung-type bond formation process that accompanied 1,2-migration of the sulfonyl groups. Investigation of the reaction mechanism showed that other nucleopiles may also promote this reaction instead of NHC. Actually, the triphenylphosphine w

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Yinli WangNominated as an outstanding PhD thesis by Kyoto University.Provides comprehensive information on N-heterocyclic carbenes.Offers practical guidance on the design and optimization of catalytic reaction

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Development of a New Heterocycle-Forming Reaction and Kinetic Resolution with N-Heterocyclic Carbene978-981-13-9398-3Series ISSN 2190-5053 Series E-ISSN 2190-5061

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Erbrecht,talyst was described. . Chiral recognization of substrate–cocatalyst complex is the crux of this reaction. Further transformation using the resulting enantiopure α-hydroxy thioamide was also investigated.

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