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Titlebook: Cyclometalation Reactions; Five-Membered Ring P Iwao Omae Book 2014 Springer Japan 2014 Agostic Interaction.C-H Activation.C-H Functionaliz

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发表于 2025-3-21 18:03:59 | 显示全部楼层 |阅读模式
书目名称Cyclometalation Reactions
副标题Five-Membered Ring P
编辑Iwao Omae
视频videohttp://file.papertrans.cn/243/242553/242553.mp4
概述First book-length and comprehensive treatment of cyclometalation reactions.Explains the development of research in cyclometalation reactions since the 1960s.Provides many equations and schemes of reac
图书封面Titlebook: Cyclometalation Reactions; Five-Membered Ring P Iwao Omae Book 2014 Springer Japan 2014 Agostic Interaction.C-H Activation.C-H Functionaliz
描述This book provides a review of cyclometalation reactions and organometallic intramolecular-coordination five-membered ring products, the most active type of reactions in synthetic organic reactions and their products. Included is the discovery of intramolecular-coordination bonds in cyclometalation reactions and the characteristics of those reactions, as well as the reasons that their five-membered ring compounds are very easily synthesized through such reactions. In addition, the applications of cyclometalation reactions and five-membered ring products, synthetic applications, catalysts, and other products are described. These topics are of special interest for industrial researchers.
出版日期Book 2014
关键词Agostic Interaction; C-H Activation; C-H Functionalization; C-X Activation; Chelate Effect; Coordination
版次1
doihttps://doi.org/10.1007/978-4-431-54604-7
isbn_softcover978-4-431-56146-0
isbn_ebook978-4-431-54604-7
copyrightSpringer Japan 2014
The information of publication is updating

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发表于 2025-3-21 23:31:30 | 显示全部楼层
The First Discovery of Intramolecular-Coordination Bonds in Cyclometalation Reactions,c acid esters with tinfoil based on IR spectra data in 1966. The stereoisomers of these reaction products were resolved into two kinds of stereoisomers by the use of mixed solvents, and each of the two structures of these stereoisomers was determined by X-ray diffraction studies in 1968 and 1969, re
发表于 2025-3-22 01:24:51 | 显示全部楼层
Verification of the Formation of Intramolecular-Coordination Bonds in Cyclometalation Reactions wita 1963 article on the reaction of an azobenzene with a nickel compound. However, the verification of the intramolecular bond was incorrectly assigned in that article as the N=N π-coordination bond to the nickel atom. For this reason, an article on the reaction of azobenzene with a Pd or Pt atom publ
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Characteristics of Cyclometalation Reactions for Organometallic Intramolecular-Coordination Five-Meis high reaction rates. Many reactions consequently proceed under mild reaction conditions, and their reaction products are very easily isolated from the reaction mixtures, since five-membered rings are generally stable. Many kinds of metal elements, a total of 69 kinds of both transition metal and
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发表于 2025-3-22 19:44:59 | 显示全部楼层
Applications of Cyclometalation Reactions and Five-Membered Ring Products for Synthetic Purposes,ed ring products by cyclometalation reactions. The second is synthesis of the derivatives of five-membered ring products or their intermediates during cyclometalation reactions. Pincer products are also used for synthesis of their derivatives.
发表于 2025-3-23 01:06:56 | 显示全部楼层
Concluding Remarks,roceed extremely easily is that the reactions first proceed through metal activation initiated by the coordination of lone electron pair, such as N, P, O, or S, to a metal atom. This is followed by γ-C–H agostic interactions, C–H activation, and the chelate effect in this order (Eq. (6.7)). A recent
发表于 2025-3-23 03:55:22 | 显示全部楼层
Book 2014ype of reactions in synthetic organic reactions and their products. Included is the discovery of intramolecular-coordination bonds in cyclometalation reactions and the characteristics of those reactions, as well as the reasons that their five-membered ring compounds are very easily synthesized throu
发表于 2025-3-23 08:48:42 | 显示全部楼层
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