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Titlebook: Cyclodextrin Chemistry; Myron L. Bender,Makoto Komiyama Book 1978 Springer-Verlag Berlin Heidelberg 1978 Chemical reaction.Chemistry.Cyclo

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书目名称Cyclodextrin Chemistry
编辑Myron L. Bender,Makoto Komiyama
视频video
丛书名称Reactivity and Structure: Concepts in Organic Chemistry
图书封面Titlebook: Cyclodextrin Chemistry;  Myron L. Bender,Makoto Komiyama Book 1978 Springer-Verlag Berlin Heidelberg 1978 Chemical reaction.Chemistry.Cyclo
描述Chemistry was at one time completely described in terms of collision theo­ ry, in which one molecule collided with another, sometimes producing reac­ tion. Then came the realization that enzymes which are highly efficient ca­ talysts, work by way of prior complexation, often stereospecific, which is then followed by chemical reaction. Thus, systems that exhibit "host-guest" relationships, i.e., that show complexing are being looked at an ever in­ creasing frequency. The cyclodextrins are the first and probably the most important example of compounds that exhibits complex formation. This is a book about the cyclodextrins. There are of course other compounds that exhibit "host-guest" relationships and thus bind other organic molecules, but so far they have not achieved the importance of the cyclodextrins. By their name it is obvious that cyclodextrins are cyclic compounds. The complexes that they form are therefore cyclic inclusion complexes. Because the complexes are cyclic in nature, complexation can be very strong, as op­ posed to 1t-complex, electrostatic, or apolar complexes in which complex formation is two-dimensional rather than three-dimensional. Cyclodextrins turn out to be
出版日期Book 1978
关键词Chemical reaction; Chemistry; Cyclodextrin; Oxidation; hydrolysis
版次1
doihttps://doi.org/10.1007/978-3-642-66842-5
isbn_softcover978-3-642-66844-9
isbn_ebook978-3-642-66842-5Series ISSN 0341-2377
issn_series 0341-2377
copyrightSpringer-Verlag Berlin Heidelberg 1978
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https://doi.org/10.1007/978-3-642-52492-9he amylase of . on starch and related compounds. Though cyclodextrins were discovered in 1891 by Villiers [12], the first detailed description of their preparation and isolation was made by Schardinger [13–15].
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https://doi.org/10.1007/978-3-540-72266-3pounds are included in the cavity of cyclodextrins (host) [20, 65–67]. Guest compounds range from polar reagents such as acids, amines, small ions such as ClO., SCN., and halogen anions [68] to highly apolar aliphatic and aromatic hydrocarbons and even rare gases [69]. Inclusion complexes can be for
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https://doi.org/10.1007/978-3-540-72266-3, respectively; C — P. is the covalent intermediate, which is an acyl-cyclodextrin in the hydrolyses of esters and amides and is cyclodextrin phosphate in the hydrolyses of organophosphates; P. and P. are the final products; and ., ., ., ., and . are rate constants for the various processes indicate
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Zusammenarbeit mit dem Pflegedienstly restricted cavity for the included substrate, which cavity can then serve as reaction medium, resulting in acceleration or deceleration of reaction. These kinds of catalyses are defined as noncovalent catalyses.
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