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Titlebook: Copper(I)-Catalyzed Stereoselective Borylation Reactions; Multisubstituted Alk Yu Ozawa Book 2023 The Editor(s) (if applicable) and The Aut

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楼主: Corrugate
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Philosophical Theology of Vocation,nates, could be transformed into optically active homoallylic alcohols with high diastereoselectivity. Furthermore, the effect of non-covalent interaction in the ligands on reactivity and the origin of enantioselectivity are analyzed and discussed using state-of-the-art DFT calculations.
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Assenting to , Death and That of the Other,high regioselectivity to produce the four-membered ring and diastereoselectivity of the substituents. These selectivities are related to facile allylic isomerization of the allylcopper(I) species and are kinetically determined via the intramolecular cyclization step.
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Basics of Input-Output Analysisd mechanism of the copper(I)-catalyzed borylation reactions. Those highly reactive and selective catalyst systems I developed and the deep understanding of the mechanism would benefit the further development of new reactions and catalyst systems.
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Modification of QuinoxP*-Type Bisphosphine Ligands for High-Performance Asymmetric Boryl Substitutinates, could be transformed into optically active homoallylic alcohols with high diastereoselectivity. Furthermore, the effect of non-covalent interaction in the ligands on reactivity and the origin of enantioselectivity are analyzed and discussed using state-of-the-art DFT calculations.
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Allylcopper(I) Isomerization-Enabled Copper(I)-Catalyzed Intramolecular Alkylboration of Terminal Ahigh regioselectivity to produce the four-membered ring and diastereoselectivity of the substituents. These selectivities are related to facile allylic isomerization of the allylcopper(I) species and are kinetically determined via the intramolecular cyclization step.
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Summary,d mechanism of the copper(I)-catalyzed borylation reactions. Those highly reactive and selective catalyst systems I developed and the deep understanding of the mechanism would benefit the further development of new reactions and catalyst systems.
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Book 2023tereoselectivities of the borylation reactions are attained through catalyst design and optimization. Furthermore, the selectivity-determining mechanisms are analyzed with state-of-the-art DFT and other computational methods...In this book, the author synthesizes some multi-substituted alkenyl and a
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Application of WIO to Industrial Ecologyere obtained in high yield with high regio- and stereoselectivity. Furthermore, a density functional theory (DFT)-based computational mechanistic study revealed that the π-coordination of the allenes to boryl copper(I) species and the following borylcupration is the key step for determining the regi
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