| 书目名称 | Copper(I)-Catalyzed Stereoselective Borylation Reactions | | 副标题 | Multisubstituted Alk | | 编辑 | Yu Ozawa | | 视频video | http://file.papertrans.cn/239/238176/238176.mp4 | | 概述 | Is nominated as an outstanding Ph.D. thesis by Hokkaido University.Describes development of novel multi-substituted allylic and alkenyl boronates and those synthetic methods.Provides deep insight into | | 丛书名称 | Springer Theses | | 图书封面 |  | | 描述 | .This book focuses on the development of novel functionalized organoboron compounds and those synthetic methods. High degrees of chemo-, regio-, and stereoselectivities of the borylation reactions are attained through catalyst design and optimization. Furthermore, the selectivity-determining mechanisms are analyzed with state-of-the-art DFT and other computational methods...In this book, the author synthesizes some multi-substituted alkenyl and allylic boronates via borylation reactions using a copper(I)/diboron catalyst system. Those compounds contain novel densely substituted and distorted structures, which have not been accessed by other methods. The high stereoselectivities are achieved by the optimization of the catalyst, especially the ligand. Some new ligands are also developed in this book. Furthermore, the derivatization of the borylation products is demonstrated to access the sterically demanding complex molecules. Also, the author performs computational analysis toreveal how the catalyst controls the selectivities. The deep insight into the reaction mechanism provides guides for rational catalyst design for not only copper(I) catalysis but also other transition metal cat | | 出版日期 | Book 2023 | | 关键词 | Borylation Reaction; Copper(I) catalysis; Stereoselective reaction; Computational study on catalyst and | | 版次 | 1 | | doi | https://doi.org/10.1007/978-981-99-1098-4 | | isbn_softcover | 978-981-99-1100-4 | | isbn_ebook | 978-981-99-1098-4Series ISSN 2190-5053 Series E-ISSN 2190-5061 | | issn_series | 2190-5053 | | copyright | The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapor |
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