| 书目名称 | Collision Theory and Statistical Theory of Chemical Reactions |
| 编辑 | Stefan G. Christov |
| 视频video | |
| 丛书名称 | Lecture Notes in Chemistry |
| 图书封面 |  |
| 描述 | Since the discovery of quantum mechanics,more than fifty years ago,the theory of chemical reactivity has taken the first steps of its development. The knowledge of the electronic structure and the properties of atoms and molecules is the basis for an un derstanding of their interactions in the elementary act of any chemical process. The increasing information in this field during the last decades has stimulated the elaboration of the methods for evaluating the potential energy of the reacting systems as well as the creation of new methods for calculation of reaction probabili ties (or cross sections) and rate constants. An exact solution to these fundamental problems of theoretical chemistry based on quan tum mechanics and statistical physics, however, is still impossible even for the simplest chemical reactions. Therefore,different ap proximations have to be used in order to simplify one or the other side of the problem. At present, the basic approach in the theory of chemical reactivity consists in separating the motions of electrons and nu clei by making use of the Born-Oppenheimer adiabatic approximation to obtain electronic energy as an effective potential for nuclear mot |
| 出版日期 | Textbook 1980 |
| 关键词 | Activation energy; Chemische Reaktion; Cross section; Quantenchemie; Reactions; chemistry; energy; heat; inf |
| 版次 | 1 |
| doi | https://doi.org/10.1007/978-3-642-93142-0 |
| isbn_softcover | 978-3-540-10012-6 |
| isbn_ebook | 978-3-642-93142-0Series ISSN 0342-4901 Series E-ISSN 2192-6603 |
| issn_series | 0342-4901 |
| copyright | Springer-Verlag Berlin Heidelberg 1980 |
发表于 2025-3-21 18:38:49
