书目名称 | Chemical Kinetics of Homogeneous Systems | 编辑 | Robert Schaal | 视频video | | 图书封面 |  | 描述 | Chemical kinetics aims to explain the factors governing the change with time of chemical systems. The results enable one to define optimum technico-economic condi tions (such as the choice of batch or continuous processes; of concentration, temperature, and pressure; of whether to use a catalyst) for the preparation of products, so that kinetics is intimately bound up with many processes of chemical industry (production, explosions, combustion, propulsion in air and in space). On another level, kinetic studies are indispensable for understanding reaction mechanisms, which implies a de tailed knowledge of the different chemical intermediates (possibly very transitory) of a chemical reaction. But in practice it is rarely possible to work with microscopic quantities of reagents and, with the exception of crossed molecular beams, all methods give only statistical results concerning a large number of molecules. Because of this restriction, it has not always been possible to establish conclusively a reaction mechanism, even for reactions ap parently simple. Numerous attempts have been made to calculate rate constants from the physical properties of the participating molecules; but the | 出版日期 | Book 1974 | 关键词 | experiment; kinetics; phase; reactions | 版次 | 1 | doi | https://doi.org/10.1007/978-94-010-2201-9 | isbn_softcover | 978-94-010-2203-3 | isbn_ebook | 978-94-010-2201-9 | copyright | D. Reidel Publishing Company, Dordrecht, Holland 1974 |
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