Titlebook: Cement-Based Materials for Nuclear Waste Storage; Florence Bart,Céline Cau-di-Coumes,Sylvie Lorente Book 2013 Springer Science+Business Me

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https://doi.org/10.1007/978-3-030-95820-6sted that the same mechanism controls Np(IV,V) uptake by these phases. The present study is complementary to earlier ones carried out in our research group and demonstrates that information on the coordination environment of actinides is essential with the aim of developing a mechanistic understandi

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https://doi.org/10.1007/978-3-030-19894-7 basis supporting the data selection was established at several meetings of an international panel of experts who reviewed and endorsed the data selection. To this end, the sorption data were checked for reliability, appropriateness for the conditions expected for the Dessel disposal facility, data

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A. N. Soloviev,N. D. T. Giang,S.-H. Changrrier. Hydrogen gas can be formed either via radiolysis or anaerobic corrosion. We therefore have two main electron donors to participate in redox reactions within an “unnaturally” high pH environment. Oxygen, present during the exploitation phase, is quickly consumed and not considered to diffuse s

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Application of a Sub-lattice Model to Predictions of Cement Hydrate Chemistryn solid and aqueous phases is explored over a range of activities and temperatures, ultimately bounded by the appearance of solubility limiting phases..Extending this approach to more realistic cement mineral assemblages introduces both stoichiometric hydrates and an additional solid solution repres

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Characterization and Solubility Determination of the Solid-Solution Between AFm-I2 and AFm-SO4ndicate the formation of a single AFm phase at every I./SO. ratio, whereby the interlayer distance increases with increasing the I./SO. ratio. This finding shows the existence of a continuous solid solution series between AFm-I. and AFm-SO. end members. The iodine uptake mechanism in AFm-SO. was als

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Coupled Mechanical and Chemo-Transport Model for the Simulation of Cementitious Materials Subjected ted from the volume of formed ettringite is introduced for directly reproducing these expansions. Explicit upscaling techniques applied on a simplified representation of the materials allow estimating both mechanical and diffusive properties of the evolving microstructure. Finally, simulations of la

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