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Titlebook: Catalytic Technology for Selective Hydrogenation of Benzene to Cyclohexene; Zhongyi Liu,Shouchang Liu,Zhongjun Li Book 2020 Science Press

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An Overview of the Catalytic Selective Hydrogenation Technologies of Benzene into Cyclohexene,xanone, adipic acid, hexanolactam, nylon 6, nylon 66, and high value fine chemicals of medicine, pesticide, and perfumes are of great significance for the economic development. Compared with the traditional process of benzene, hydrogenation into cyclohexane is safe, resource saving, environmentally
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Benzene Selective Hydrogenation Thermodynamics, Heterogeneous Catalytic Kinetics Catalysis Mechanisged through multiphase catalysis and the high selectivity of cyclohexene under the high conversion of benzene. The thermodynamic results reveal that the selective hydrogenation of benzene should proceed under suitable temperature and pressure.
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,The First-Generation Catalyst for Selective Hydrogenation of Benzene to Cyclohexene-Ru–M–B/ZrO2(M=Fechnologies were transferred to our country in 1995 and 2005, respectively. The main technical indexes of the first-generation catalyst were as follows: the conversion of benzene was 40%, the selectivity of cyclohexene was 80%, and the yield of cyclohexene was 32%. For the second-generation catalyst
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The Second-Generation Catalyst for Selective Hydrogenation of Benzene to Cyclohexene-Ru-Zn-Na2SiO3-of cyclohexene was over 80%, yield of cyclohexene was more than 42%, reached the second-generation of similar catalyst level abroad. Compared with the first generation amorphous alloy Ru-M-B/ZrO., the second-generation catalyst belongs to the crystalline structure with better thermal stability and l
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Catalyst Deactivation and Regeneration in Benzene Selective Hydrogenation,loading of Ru catalyst is 200–400 kg for benzene selective hydrogenation, the life expectancy of the catalyst is about 2 years. During the operation of the device, the loss will be significant when the catalyst is inactivated due to improper operation or the introduction of impurities. If the deacti
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Selective Hydrogenation of Benzene to Cyclohexene and Incorporate Device of Its Downstream Productsn the patented invention patent, “A device of benzene selective hydrogenation” is conducive to control the reaction temperature and improve the reaction rate, and thus the catalyst has high selectivity and cyclohexene yield.
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