Titlebook: Boron and Refractory Borides; Vlado I. Matkovich Book 1977 Springer-Verlag Berlin Heidelberg 1977 Beryllium.alkali metal.boron.carbon.chem

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Characterization of the Logistics Conceptionthose in which boron atoms occupy the twelve vertices of an icosahedron or cubo-octahedron are the most common, although an octahedral unit consisting of six boron atoms at the vertices is well known and is characteristic of the hexaborides and tetraborides. This review is concerned with establishin

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Characterization of the Logistics Conceptionds with atoms of the same octahedron and the fifth one points outwards along one of the A. axes of the octahedron. The presence of this fifth bond is responsible for the occurrence of the three-dimensional structure. Only two families of boron-rich borides have structures based on the B. octahedron:

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https://doi.org/10.1007/3-540-27516-9d red boron crystals in the deposit formed under the pyrolysis of boron triiodide. However, as DECKER and KASPER (1959) stated, α-boron had earlier been prepared by the decomposition of boron hydride and had also been found in some commercially prepared boron samples.

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https://doi.org/10.1007/3-540-27516-9 boron by reduction of several boron compounds (boron oxide, boron fluoride and fluoborates by alkali metals) (Gay-Lussac and Thénard, 1808; Davy, 1811; Wöhler and Sainte-Claire Deville, 1858; Rawson, 1888).

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https://doi.org/10.1007/978-3-658-42837-2ization of the stability of these materials as well as the metal-deficient and mixed-metal phases. Band structure and density-of-states calculations lead to values of electrical conductivities and Hall coefficients for these materials which agree well with experimental data.