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Titlebook: Biochemistry of Dioxygen; Llyod L. Ingraham,Damon L. Meyer Book 1985 Plenum Press, New York 1985 Alanin.Amino acid.Galactose.Lipid.Oxidati

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发表于 2025-3-23 10:36:53 | 显示全部楼层
Dioxygenases,atalyzes the aerobic oxidation of fatty acids, particularly linoleic acid, to the hydroperoxides. More specifically, lipoxygenase catalyzes the oxidation of .-1,4-pentadienes to the hydroperoxides of .- l,3-dienes (Figure 18–2).
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Wolfgang Becker,Robert Holzmannound state (Kasha and Khan, 1970). An orbital momentum of 0 gives a Σ state; an orbital momentum of 1, a π state; and an orbital momentum of 2, a Δ state. The lower singlet state has an orbital momentum of 2 and is therefore a Δ state; the other has an orbital moment of 0 and is therefore a Σ state.
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https://doi.org/10.1007/978-3-642-59427-4perform aromatic hydroxylations, oxidative decarboxylations, and oxidation of amines. Flavin monooxygenases are not able to hydroxylate aliphatic hydrocarbons, and most, if not all, aromatic substrates are fairly well activated by hydroxy or amino groups.
发表于 2025-3-24 04:12:37 | 显示全部楼层
Singlet Dioxygen,ound state (Kasha and Khan, 1970). An orbital momentum of 0 gives a Σ state; an orbital momentum of 1, a π state; and an orbital momentum of 2, a Δ state. The lower singlet state has an orbital momentum of 2 and is therefore a Δ state; the other has an orbital moment of 0 and is therefore a Σ state.
发表于 2025-3-24 08:21:05 | 显示全部楼层
Flavin Monooxygenases,perform aromatic hydroxylations, oxidative decarboxylations, and oxidation of amines. Flavin monooxygenases are not able to hydroxylate aliphatic hydrocarbons, and most, if not all, aromatic substrates are fairly well activated by hydroxy or amino groups.
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Cytochrome P-450,tions (Bjorkhem and Danielson, 1970; Ellin.., 1972; Ichihara et al., 1979). Either cytochrome P-450 or similar iron-containing monooxygenases cleave inositol to n-glucuronic acid (Charalampous, 1959, 1960).
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